Thermal decomposition of tetrazole-containing polymers. IV: poly-1-vinyl-5-methyltetrazole and poly-1-vinyl-5-phenyltetrazole
Publication type: Journal Article
Publication date: 1994-01-01
scimago Q1
wos Q1
SJR: 1.237
CiteScore: 11.3
Impact factor: 7.4
ISSN: 01413910, 18732321
Materials Chemistry
Condensed Matter Physics
Polymers and Plastics
Mechanics of Materials
Abstract
The thermal decomposition of poly-1-vinyl-5-methyltetrazole (P-1VMT) and poly-1-vinyl-5-phenyltetrazole (P-1VPT) was studied by high resolution thermogravimetry (HRTG) differential scanning calorimetry (DSC) and thermal volatilization analysis (TVA). Solid residues, high boiling products, and gases were collected at different stages of the thermal decomposition and identified by FTIR and/or GC-MS. Both P-1VMT and P-1VPT show complex multistep decomposition on progressive heating. The thermal decomposition starts from degradation of tetrazole pendant groups. At the beginning, P-1VMT presumably eliminates acetonitrile, whereas P-1VPT eliminates nitrogen. On further heating, the partially decomposed polymers melt and an evolution of the pendant groups (5-methyltetrazole and 5-phenyltetrazole) is observed. Thermal fragmentation of the polymeric chain occurs at high temperatures (≥320°C).
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Total citations:
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Citations from 2024:
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(37.5%)
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Levchik S. et al. Thermal decomposition of tetrazole-containing polymers. IV: poly-1-vinyl-5-methyltetrazole and poly-1-vinyl-5-phenyltetrazole // Polymer Degradation and Stability. 1994. Vol. 46. No. 2. pp. 225-234.
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Levchik S., Ivashkevich O. A., Costa L., Gaponik P., Andreeva T. N. Thermal decomposition of tetrazole-containing polymers. IV: poly-1-vinyl-5-methyltetrazole and poly-1-vinyl-5-phenyltetrazole // Polymer Degradation and Stability. 1994. Vol. 46. No. 2. pp. 225-234.
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RIS
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TY - JOUR
DO - 10.1016/0141-3910(94)90054-x
UR - https://doi.org/10.1016/0141-3910(94)90054-x
TI - Thermal decomposition of tetrazole-containing polymers. IV: poly-1-vinyl-5-methyltetrazole and poly-1-vinyl-5-phenyltetrazole
T2 - Polymer Degradation and Stability
AU - Levchik, S.V.
AU - Ivashkevich, Oleg A.
AU - Costa, L.
AU - Gaponik, P.N.
AU - Andreeva, T N
PY - 1994
DA - 1994/01/01
PB - Elsevier
SP - 225-234
IS - 2
VL - 46
SN - 0141-3910
SN - 1873-2321
ER -
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BibTex (up to 50 authors)
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@article{1994_Levchik,
author = {S.V. Levchik and Oleg A. Ivashkevich and L. Costa and P.N. Gaponik and T N Andreeva},
title = {Thermal decomposition of tetrazole-containing polymers. IV: poly-1-vinyl-5-methyltetrazole and poly-1-vinyl-5-phenyltetrazole},
journal = {Polymer Degradation and Stability},
year = {1994},
volume = {46},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/0141-3910(94)90054-x},
number = {2},
pages = {225--234},
doi = {10.1016/0141-3910(94)90054-x}
}
Cite this
MLA
Copy
Levchik, S.V., et al. “Thermal decomposition of tetrazole-containing polymers. IV: poly-1-vinyl-5-methyltetrazole and poly-1-vinyl-5-phenyltetrazole.” Polymer Degradation and Stability, vol. 46, no. 2, Jan. 1994, pp. 225-234. https://doi.org/10.1016/0141-3910(94)90054-x.