Asymmetric synthesis of 4-vinylcyclohexene using modified nickel catalysts
1
MPI für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-4330 Mülheim/Ruhr F.R.G.
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Publication type: Journal Article
Publication date: 1981-11-01
scimago Q4
SJR: 0.140
CiteScore: 1.2
Impact factor: —
ISSN: 10013555, 03045102
General Engineering
Abstract
Optically active phosphines and cyclic phosphonites are used in the catalytic system Ni(O)/ligand/butadiene. The formation of 4-vinylcyclohexene as the only chiral dimer is monitored by the induced optical activity, and widely depends on the relative concentration and the nature of the ligands. The highest induction (35% e.e.) is found at 20 °C with 2-t-butyl-4,5-dicarbethoxy-1,3,2-dioxaphospholane.
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Jürgen Richter W. Asymmetric synthesis of 4-vinylcyclohexene using modified nickel catalysts // Journal of Molecular Catalysis. 1981. Vol. 13. No. 2. pp. 201-206.
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Jürgen Richter W. Asymmetric synthesis of 4-vinylcyclohexene using modified nickel catalysts // Journal of Molecular Catalysis. 1981. Vol. 13. No. 2. pp. 201-206.
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RIS
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TY - JOUR
DO - 10.1016/0304-5102(81)85020-1
UR - https://doi.org/10.1016/0304-5102(81)85020-1
TI - Asymmetric synthesis of 4-vinylcyclohexene using modified nickel catalysts
T2 - Journal of Molecular Catalysis
AU - Jürgen Richter, Wolf
PY - 1981
DA - 1981/11/01
PB - Elsevier
SP - 201-206
IS - 2
VL - 13
SN - 1001-3555
SN - 0304-5102
ER -
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@article{1981_Jürgen Richter,
author = {Wolf Jürgen Richter},
title = {Asymmetric synthesis of 4-vinylcyclohexene using modified nickel catalysts},
journal = {Journal of Molecular Catalysis},
year = {1981},
volume = {13},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/0304-5102(81)85020-1},
number = {2},
pages = {201--206},
doi = {10.1016/0304-5102(81)85020-1}
}
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MLA
Copy
Jürgen Richter, Wolf. “Asymmetric synthesis of 4-vinylcyclohexene using modified nickel catalysts.” Journal of Molecular Catalysis, vol. 13, no. 2, Nov. 1981, pp. 201-206. https://doi.org/10.1016/0304-5102(81)85020-1.