volume 81 issue 2 pages 207-214

Ruthenium complex-catalyzed hydrosilylation of allyl chloride with trimethoxysilane

MASATO TANAKA
Teruyuki Hayashi
Zhi Yuan Mi
Publication typeJournal Article
Publication date1993-05-01
scimago Q4
SJR0.140
CiteScore1.2
Impact factor
ISSN10013555, 03045102
General Engineering
Abstract
The hydrosilylation of allyl chloride with trimethoxysilane has been examined in the presence of several homogeneous complex catalysts. Iridium and ruthenium complexes exhibit higher selectivities in the reaction to give 3-chloropropyltrimethoxysilane. Other complexes usually give propylene and/or tetramethoxysilane as side products in large quantities. The Ru 3 (CO) 12 ,-catalyzed reactions effected at lower temperatures or by using a large excess of trimethoxysilane relative to allyl chloride give the chloropropylsilane in good yields.
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GOST |
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GOST Copy
TANAKA M., Hayashi T., Mi Z. Y. Ruthenium complex-catalyzed hydrosilylation of allyl chloride with trimethoxysilane // Journal of Molecular Catalysis. 1993. Vol. 81. No. 2. pp. 207-214.
GOST all authors (up to 50) Copy
TANAKA M., Hayashi T., Mi Z. Y. Ruthenium complex-catalyzed hydrosilylation of allyl chloride with trimethoxysilane // Journal of Molecular Catalysis. 1993. Vol. 81. No. 2. pp. 207-214.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/0304-5102(93)80007-h
UR - https://doi.org/10.1016/0304-5102(93)80007-h
TI - Ruthenium complex-catalyzed hydrosilylation of allyl chloride with trimethoxysilane
T2 - Journal of Molecular Catalysis
AU - TANAKA, MASATO
AU - Hayashi, Teruyuki
AU - Mi, Zhi Yuan
PY - 1993
DA - 1993/05/01
PB - Elsevier
SP - 207-214
IS - 2
VL - 81
SN - 1001-3555
SN - 0304-5102
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1993_TANAKA,
author = {MASATO TANAKA and Teruyuki Hayashi and Zhi Yuan Mi},
title = {Ruthenium complex-catalyzed hydrosilylation of allyl chloride with trimethoxysilane},
journal = {Journal of Molecular Catalysis},
year = {1993},
volume = {81},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/0304-5102(93)80007-h},
number = {2},
pages = {207--214},
doi = {10.1016/0304-5102(93)80007-h}
}
MLA
Cite this
MLA Copy
TANAKA, MASATO, et al. “Ruthenium complex-catalyzed hydrosilylation of allyl chloride with trimethoxysilane.” Journal of Molecular Catalysis, vol. 81, no. 2, May. 1993, pp. 207-214. https://doi.org/10.1016/0304-5102(93)80007-h.