Physica C: Superconductivity and its Applications

, volume 215 , issue 1-2 , pages 1-10

The synthesis and characterization of the HgBa2Ca2Cu3O8+δ and HgBa2Ca3Cu4O10+δ phases

Evgeny V. Antipov ^{1, 2}

S. M. Loureiro ³

C. Chaillout ³

J.J. Capponi ³

Pierre Bordet ³

J. L. Tholence ⁴

S. N. Putilin ⁵

M. MAREZIO ^{3, 6}

Hide authors affiliations Show authors affiliations: 6 affiliations

Department of Chemistry, Moscow State University, 119899 Moscow, Russian Federation |

Laboratoire de Cristallographie CNRS-UJF, BP 166, 38042 Grenoble Cedex 09, France |

Laboratoire de Cristallographie, CNRS-UJF, BP 166, 38042 Grenoble cedex 09, France |

⁴

CRTBT-CNRS-UJF, BP 166, 38042 Grenoble Cedex 09, France |

⁵

Department of Chemistry, Moscow State University, 119899 Moscow, Russian Federation. |

⁶

AT&T Bell Laboratories, Murray Hill, NJ 07974, USA |

Publication type: Journal Article

Publication date: 1993-09-01

Elsevier

Physica C: Superconductivity and its Applications

scimago Q3

wos Q4

SJR: 0.313

CiteScore: 2.4

Impact factor: 1.0

ISSN: 09214534, 18732143

DOI: 10.1016/0921-4534(93)90358-W

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Electronic, Optical and Magnetic Materials

Condensed Matter Physics

Electrical and Electronic Engineering

Energy Engineering and Power Technology

Abstract

Abstract The third (Hg-1223) and the fourth (Hg-1234) members of the recently-discovered homologous series HgBa2Can−1CunO2n+2+δ have been synthesized by solid state reaction, carried out at 950°C under 50 kbar at different annealing times. These phases have a tetragonal cell with lattice parameters: a = 3.8532 (6) A , c = 15.818(2) A , and a = 3.8540(3) A , c = 19.006 (3) A , respectively. The c parameters are in agreement with the formula c ≌ 9.5 + 3.2 (n − 1). Electron microscopy study showed similar lattice parameters as well as the occurence of different intergrowths and stacking faults. A periodicity of 22 A has also been detected, which may be attributed to the existence of the Hg-1245 phase. EDS analysis data of several grains of Hg-1223 and Hg-1234 are in agreement with the proposed chemical formulae. AC susceptibility measurements show that an increase of the superconducting transition temperature with n in the HgBa2Can−1CunO2n+2+δ series occurs till the third member, after which a saturation seems to be achieved.

Found

13 citations

Antipov Evgeny

DSc in Chemistry, professor, full member of the Russian Academy of Sciences

463 publications, 10 536 citations, 29 reviews

h-index: 48

Lomonosov Moscow State University

Skolkovo Institute of Science and Technology

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Antipov E. V. et al. The synthesis and characterization of the HgBa2Ca2Cu3O8+δ and HgBa2Ca3Cu4O10+δ phases // Physica C: Superconductivity and its Applications. 1993. Vol. 215. No. 1-2. pp. 1-10.

GOST all authors (up to 50) Copy

Antipov E. V., Loureiro S. M., Chaillout C., Capponi J., Bordet P., Tholence J. L., Putilin S. N., MAREZIO M. The synthesis and characterization of the HgBa2Ca2Cu3O8+δ and HgBa2Ca3Cu4O10+δ phases // Physica C: Superconductivity and its Applications. 1993. Vol. 215. No. 1-2. pp. 1-10.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/0921-4534(93)90358-W

UR - https://linkinghub.elsevier.com/retrieve/pii/092145349390358W

TI - The synthesis and characterization of the HgBa2Ca2Cu3O8+δ and HgBa2Ca3Cu4O10+δ phases

T2 - Physica C: Superconductivity and its Applications

AU - Antipov, Evgeny V.

AU - Loureiro, S. M.

AU - Chaillout, C.

AU - Capponi, J.J.

AU - Bordet, Pierre

AU - Tholence, J. L.

AU - Putilin, S. N.

AU - MAREZIO, M.

PY - 1993

DA - 1993/09/01

PB - Elsevier

SP - 1-10

IS - 1-2

VL - 215

SN - 0921-4534

SN - 1873-2143

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{1993_Antipov,

author = {Evgeny V. Antipov and S. M. Loureiro and C. Chaillout and J.J. Capponi and Pierre Bordet and J. L. Tholence and S. N. Putilin and M. MAREZIO},

title = {The synthesis and characterization of the HgBa2Ca2Cu3O8+δ and HgBa2Ca3Cu4O10+δ phases},

journal = {Physica C: Superconductivity and its Applications},

year = {1993},

volume = {215},

publisher = {Elsevier},

month = {sep},

url = {https://linkinghub.elsevier.com/retrieve/pii/092145349390358W},

number = {1-2},

pages = {1--10},

doi = {10.1016/0921-4534(93)90358-W}

}

MLA

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MLA Copy

Antipov, Evgeny V., et al. “The synthesis and characterization of the HgBa2Ca2Cu3O8+δ and HgBa2Ca3Cu4O10+δ phases.” Physica C: Superconductivity and its Applications, vol. 215, no. 1-2, Sep. 1993, pp. 1-10. https://linkinghub.elsevier.com/retrieve/pii/092145349390358W.