NEW CHIRAL SYNTHONS FROM THE MICROBIAL OXIDATION OF BROMONAPHTHALENES
Publication type: Journal Article
Publication date: 1996-01-01
Catalysis
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
1-Bromo- and 2-bromonaphthalene were subjected to bio-oxidation with whole cells of Pseudomonas putida NCIB 9816-11. The major metabolites were isolated and spectroscopically characterized as (+)- cis -( 1R,2S )-Dihydroxy-1,2-dihydro-8-bromonaphthalene 1 , (+)- cis -( 1R,2S -Dihydroxy-1,2-dihydro-5-bromonaphthalene 2 from 1-bromo-naphthalene and (+)- cis -( 1R,2S )-Dihydroxy-1,2-dihydro-7-bromonaphthalene 8 from 2-bromonaphthalene. The absolute stereochemistry and enantiomeric excess were determined by conversion of each metabolite to the known (−)- cis -tetrahydronaphthalene diol 6 .
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GOST
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Hudlicky T. et al. NEW CHIRAL SYNTHONS FROM THE MICROBIAL OXIDATION OF BROMONAPHTHALENES // Tetrahedron Asymmetry. 1996. Vol. 7. No. 1. pp. 61-68.
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Hudlicky T., Endoma M. A. A., Butora G. NEW CHIRAL SYNTHONS FROM THE MICROBIAL OXIDATION OF BROMONAPHTHALENES // Tetrahedron Asymmetry. 1996. Vol. 7. No. 1. pp. 61-68.
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RIS
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TY - JOUR
DO - 10.1016/0957-4166(95)00421-1
UR - https://doi.org/10.1016/0957-4166(95)00421-1
TI - NEW CHIRAL SYNTHONS FROM THE MICROBIAL OXIDATION OF BROMONAPHTHALENES
T2 - Tetrahedron Asymmetry
AU - Hudlicky, Tomas
AU - Endoma, Mary Ann A
AU - Butora, Gabor
PY - 1996
DA - 1996/01/01
PB - Elsevier
SP - 61-68
IS - 1
VL - 7
SN - 0957-4166
SN - 1362-511X
ER -
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BibTex (up to 50 authors)
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@article{1996_Hudlicky,
author = {Tomas Hudlicky and Mary Ann A Endoma and Gabor Butora},
title = {NEW CHIRAL SYNTHONS FROM THE MICROBIAL OXIDATION OF BROMONAPHTHALENES},
journal = {Tetrahedron Asymmetry},
year = {1996},
volume = {7},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/0957-4166(95)00421-1},
number = {1},
pages = {61--68},
doi = {10.1016/0957-4166(95)00421-1}
}
Cite this
MLA
Copy
Hudlicky, Tomas, et al. “NEW CHIRAL SYNTHONS FROM THE MICROBIAL OXIDATION OF BROMONAPHTHALENES.” Tetrahedron Asymmetry, vol. 7, no. 1, Jan. 1996, pp. 61-68. https://doi.org/10.1016/0957-4166(95)00421-1.