Inorganica Chimica Acta, volume 507, pages 119589
The method for synthesis of 2-sulfonium closo-decaborate anions derivatives with exo-polyhedral aminogroups
Publication type: Journal Article
Publication date: 2020-07-01
Journal:
Inorganica Chimica Acta
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 2.8
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
• Alkylation of [2-B 10 H 9 SH] 2− with n -bromoalkyl phthalimides are studied. • Chlorination of Bu 4 N[B 10 H 9 S((CH 2 ) n N(CO) 2 C 6 H 4 ) 2 ] ( n = 1–3) are conducted. • Sulfonium derivatives of the closo -decaborate anion with amino groups were developed. A method for the preparation of sulfonium derivatives of the closo -decaborate anion with the exo- polyhedral amino groups [B 10 H 9 S((CH 2 ) n NH 2 ) 2 ] – ( n = 1–3) has been developed. The method is based on the alkylation of the [B 10 H 9 SH] 2– anion with N- bromoalkyl phthalimides and subsequent removal of the phthalimide protection with hydrazine. We could show that the interaction between the [B 10 H 9 SH] 2– anion with bromomethyl phthalimide groups allowed us to prepare selectively mono-S-substituted sulfanyl derivatives [B 10 H 9 SCH 2 N(CO) 2 C 6 H 4 ] 2– . Due to the high stability of the sulfonium derivatives of the closo -decaborate anion, it is possible to obtain pechlorinated analogs of these compounds by chlorination of the salts n- Bu 4 N[B 10 H 9 S((CH 2 ) n N(CO) 2 C 6 H 4 ) 2 ] ( n = 1–3) with sulfuryl chloride in acetonitrile.
Citations by journals
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Russian Journal of Inorganic Chemistry
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3 publications, 20%
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2 publications, 13.33%
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Inorganica Chimica Acta
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Inorganica Chimica Acta
1 publication, 6.67%
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Molecules
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1 publication, 6.67%
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Polyhedron
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Polyhedron
1 publication, 6.67%
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Inorganic Chemistry
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1 publication, 6.67%
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Journal of Molecular Structure
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Journal of Molecular Structure
1 publication, 6.67%
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
1 publication, 6.67%
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Russian Journal of Organic Chemistry
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Russian Journal of Organic Chemistry
1 publication, 6.67%
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ChemistrySelect
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ChemistrySelect
1 publication, 6.67%
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1
2
3
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Citations by publishers
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5
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Elsevier
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Elsevier
5 publications, 33.33%
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Pleiades Publishing
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Pleiades Publishing
5 publications, 33.33%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 6.67%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
1 publication, 6.67%
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Wiley
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Wiley
1 publication, 6.67%
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5
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Kubasov A. S. et al. The method for synthesis of 2-sulfonium closo-decaborate anions derivatives with exo-polyhedral aminogroups // Inorganica Chimica Acta. 2020. Vol. 507. p. 119589.
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Kubasov A. S., Turishev E. S., Golubev A. E., Bykov A. Yu., Zhizhin K. Y., Kuznetsov N. T. The method for synthesis of 2-sulfonium closo-decaborate anions derivatives with exo-polyhedral aminogroups // Inorganica Chimica Acta. 2020. Vol. 507. p. 119589.
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TY - JOUR
DO - 10.1016/J.ICA.2020.119589
UR - https://doi.org/10.1016%2FJ.ICA.2020.119589
TI - The method for synthesis of 2-sulfonium closo-decaborate anions derivatives with exo-polyhedral aminogroups
T2 - Inorganica Chimica Acta
AU - Kubasov, Alexey S.
AU - Turishev, E S
AU - Golubev, Aleksei E.
AU - Bykov, A Yu
AU - Zhizhin, Konstantin Yu.
AU - Kuznetsov, N. T.
PY - 2020
DA - 2020/07/01 00:00:00
PB - Elsevier
SP - 119589
VL - 507
SN - 0020-1693
SN - 1873-3255
ER -
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@article{2020_Kubasov,
author = {Alexey S. Kubasov and E S Turishev and Aleksei E. Golubev and A Yu Bykov and Konstantin Yu. Zhizhin and N. T. Kuznetsov},
title = {The method for synthesis of 2-sulfonium closo-decaborate anions derivatives with exo-polyhedral aminogroups},
journal = {Inorganica Chimica Acta},
year = {2020},
volume = {507},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016%2FJ.ICA.2020.119589},
pages = {119589},
doi = {10.1016/J.ICA.2020.119589}
}