Journal of Fluorine Chemistry, volume 43, issue 1, pages 131-144
Nucleophilic substitution of pentafluorobenzes with imidazole
Publication type: Journal Article
Publication date: 1989-04-01
Journal:
Journal of Fluorine Chemistry
Quartile SCImago
Q3
Quartile WOS
Q3
SJR: 0.355
CiteScore: 3.8
Impact factor: 1.7
ISSN: 00221139
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Environmental Chemistry
Abstract
The imidazole substitution of pentafluorobenzenes C6F5R: R = CN, NO2, CO2C2H5, CHO, I, Br, Cl, H) occurred mainly at the para -position to R and corresponding 1-(4′-R-tetrafluorophenyl)imidazoles were obtained in good yields. The reactivity varied markedly with the substituents: nitro- or cyanopentafluorobenzene easily reacted at ambient temperature without any bases; however, methyl- or methoxypentafluorobenzene failed to react even at 100°C in the presence of a strong base.
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Cite this
GOST
Copy
FUJII S., Maki Y., Kimoto H. Nucleophilic substitution of pentafluorobenzes with imidazole // Journal of Fluorine Chemistry. 1989. Vol. 43. No. 1. pp. 131-144.
GOST all authors (up to 50)
Copy
FUJII S., Maki Y., Kimoto H. Nucleophilic substitution of pentafluorobenzes with imidazole // Journal of Fluorine Chemistry. 1989. Vol. 43. No. 1. pp. 131-144.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/S0022-1139(00)81642-5
UR - https://doi.org/10.1016/S0022-1139(00)81642-5
TI - Nucleophilic substitution of pentafluorobenzes with imidazole
T2 - Journal of Fluorine Chemistry
AU - FUJII, SHOZO
AU - Maki, Yasuo
AU - Kimoto, Hiroshi
PY - 1989
DA - 1989/04/01
PB - Elsevier
SP - 131-144
IS - 1
VL - 43
SN - 0022-1139
ER -
Cite this
BibTex
Copy
@article{1989_FUJII,
author = {SHOZO FUJII and Yasuo Maki and Hiroshi Kimoto},
title = {Nucleophilic substitution of pentafluorobenzes with imidazole},
journal = {Journal of Fluorine Chemistry},
year = {1989},
volume = {43},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/S0022-1139(00)81642-5},
number = {1},
pages = {131--144},
doi = {10.1016/S0022-1139(00)81642-5}
}
Cite this
MLA
Copy
FUJII, SHOZO, et al. “Nucleophilic substitution of pentafluorobenzes with imidazole.” Journal of Fluorine Chemistry, vol. 43, no. 1, Apr. 1989, pp. 131-144. https://doi.org/10.1016/S0022-1139(00)81642-5.