Copper and cobalt mediated regioselective alkylation of polyketide models: methyl 3,5-dioxohexanoate and triacetic acid lactone
Publication type: Journal Article
Publication date: 1990-01-01
scimago Q3
wos Q2
SJR: 0.426
CiteScore: 4.1
Impact factor: 2.2
ISSN: 00404020, 14645416
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
Regioselective C-alkylations at the intercarbonyl positions C-4 and C-2 of the polyketide model methyl 3,5-dioxohexanoate, 1 , have been acomplished through reactions of its cobalt(II), 4a , and copper(II), 4b , complexes respectively. Some examples of double alkylations at both positions are presented. Cyclizations of the regioselectively substituted diketoesters so prepared gave triacetic acid lactone derivatives regioselectively alkylated at C-5 and at C-3.
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GOST
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Cervello J., Marquet J., Moreno-Mañas M. Copper and cobalt mediated regioselective alkylation of polyketide models: methyl 3,5-dioxohexanoate and triacetic acid lactone // Tetrahedron. 1990. Vol. 46. No. 6. pp. 2035-2046.
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Cervello J., Marquet J., Moreno-Mañas M. Copper and cobalt mediated regioselective alkylation of polyketide models: methyl 3,5-dioxohexanoate and triacetic acid lactone // Tetrahedron. 1990. Vol. 46. No. 6. pp. 2035-2046.
Cite this
RIS
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TY - JOUR
DO - 10.1016/S0040-4020(01)89770-2
UR - https://doi.org/10.1016/S0040-4020(01)89770-2
TI - Copper and cobalt mediated regioselective alkylation of polyketide models: methyl 3,5-dioxohexanoate and triacetic acid lactone
T2 - Tetrahedron
AU - Cervello, Jordi
AU - Marquet, Jorge
AU - Moreno-Mañas, Marcial
PY - 1990
DA - 1990/01/01
PB - Elsevier
SP - 2035-2046
IS - 6
VL - 46
SN - 0040-4020
SN - 1464-5416
ER -
Cite this
BibTex (up to 50 authors)
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@article{1990_Cervello,
author = {Jordi Cervello and Jorge Marquet and Marcial Moreno-Mañas},
title = {Copper and cobalt mediated regioselective alkylation of polyketide models: methyl 3,5-dioxohexanoate and triacetic acid lactone},
journal = {Tetrahedron},
year = {1990},
volume = {46},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/S0040-4020(01)89770-2},
number = {6},
pages = {2035--2046},
doi = {10.1016/S0040-4020(01)89770-2}
}
Cite this
MLA
Copy
Cervello, Jordi, et al. “Copper and cobalt mediated regioselective alkylation of polyketide models: methyl 3,5-dioxohexanoate and triacetic acid lactone.” Tetrahedron, vol. 46, no. 6, Jan. 1990, pp. 2035-2046. https://doi.org/10.1016/S0040-4020(01)89770-2.