Reaction of singlet oxygen with alkenylidenecyclopropanes: Implication for a peroxyallyl intermediate
Publication type: Journal Article
Publication date: 1990-01-01
scimago Q3
wos Q3
SJR: 0.334
CiteScore: 3.2
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
Photosensitized oxygenation of adamantenylidenecyciopropanes ( 1 ) gave either the corresponding oxetanones ( 2a-c ) or the cyclic ketones ( 4 and 5 ) depending on the substituent on the cyclopropane ring in addition to adamantanone. The results are rationalized in terms of initial formation of a perepoxide followed by that of a peroxyallyl intermediate.
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Total citations:
25
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GOST
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Akasaka T. et al. Reaction of singlet oxygen with alkenylidenecyclopropanes: Implication for a peroxyallyl intermediate // Tetrahedron Letters. 1990. Vol. 31. No. 8. pp. 1173-1176.
GOST all authors (up to 50)
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Akasaka T., MISAWA Y., Ando W. Reaction of singlet oxygen with alkenylidenecyclopropanes: Implication for a peroxyallyl intermediate // Tetrahedron Letters. 1990. Vol. 31. No. 8. pp. 1173-1176.
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RIS
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TY - JOUR
DO - 10.1016/S0040-4039(00)88757-2
UR - https://doi.org/10.1016/S0040-4039(00)88757-2
TI - Reaction of singlet oxygen with alkenylidenecyclopropanes: Implication for a peroxyallyl intermediate
T2 - Tetrahedron Letters
AU - Akasaka, Takeshi
AU - MISAWA, Yoshihisa
AU - Ando, Wataru
PY - 1990
DA - 1990/01/01
PB - Elsevier
SP - 1173-1176
IS - 8
VL - 31
SN - 0040-4039
SN - 1873-3581
ER -
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BibTex (up to 50 authors)
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@article{1990_Akasaka,
author = {Takeshi Akasaka and Yoshihisa MISAWA and Wataru Ando},
title = {Reaction of singlet oxygen with alkenylidenecyclopropanes: Implication for a peroxyallyl intermediate},
journal = {Tetrahedron Letters},
year = {1990},
volume = {31},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/S0040-4039(00)88757-2},
number = {8},
pages = {1173--1176},
doi = {10.1016/S0040-4039(00)88757-2}
}
Cite this
MLA
Copy
Akasaka, Takeshi, et al. “Reaction of singlet oxygen with alkenylidenecyclopropanes: Implication for a peroxyallyl intermediate.” Tetrahedron Letters, vol. 31, no. 8, Jan. 1990, pp. 1173-1176. https://doi.org/10.1016/S0040-4039(00)88757-2.