Poly(2-hydroxyethyl methacrylate-co-sulfobetaine)s hydrogels: 3. Synthesis and swelling behaviors of the [2-hydroxyethyl methacrylate-co-N,N′-dimethyl (acrylamido propyl) ammonium propane sulfonate] hydrogels
1
Department of Chemical Engineering, Tatung Institute of Technology, Taipei, 10451 Taiwan
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Publication type: Journal Article
Publication date: 1998-12-01
Pharmaceutical Science
General Chemical Engineering
Polymers and Plastics
Abstract
A series of the 2-hydroxyethyl methacrylate/N,N′-dimethyl-(acrylamido propyl) ammonium propane sulfonate (HEMA/DMAAPS) copolymeric gels has been prepared from various molar ratios of HEMA and the zwitterionic monomer DMAAPS. The influence of the amount of zwitterionic monomer in the copolymeric gels on the swelling behaviors in water, various saline solutions, and various temperatures was investigated. Results indicated that in the equilibrium swelling ratio ( Q eq ), the PHEMA hydrogel exhibited a minimum Q eq at 55°C. Then, the minimum Q eq was more obvious when higher zwitterionic monomer, DMAAPS, content was added into the HEMA/DMAAPS copolymeric gels. In the saline solution, the swelling ratios of HEMA/DMAAPS copolymer gels increased rapidly with increasing concentration of the salt, and with smaller ratio of charge/radius. In dynamic swelling behaviors, the PHEMA hydrogel (DM0) and the HEMA/DMAAPS copolymeric gels with lower DMAAPS content (DM1 and DM2) exhibited overshoot phenomena. The maximum overshoot value decreases with increase in temperature.
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Lee W., Chen C. Poly(2-hydroxyethyl methacrylate-co-sulfobetaine)s hydrogels: 3. Synthesis and swelling behaviors of the [2-hydroxyethyl methacrylate-co-N,N′-dimethyl (acrylamido propyl) ammonium propane sulfonate] hydrogels // Polymer Gels and Networks. 1998. Vol. 6. No. 6. pp. 493-511.
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Lee W., Chen C. Poly(2-hydroxyethyl methacrylate-co-sulfobetaine)s hydrogels: 3. Synthesis and swelling behaviors of the [2-hydroxyethyl methacrylate-co-N,N′-dimethyl (acrylamido propyl) ammonium propane sulfonate] hydrogels // Polymer Gels and Networks. 1998. Vol. 6. No. 6. pp. 493-511.
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TY - JOUR
DO - 10.1016/S0966-7822(99)00002-7
UR - https://doi.org/10.1016/S0966-7822(99)00002-7
TI - Poly(2-hydroxyethyl methacrylate-co-sulfobetaine)s hydrogels: 3. Synthesis and swelling behaviors of the [2-hydroxyethyl methacrylate-co-N,N′-dimethyl (acrylamido propyl) ammonium propane sulfonate] hydrogels
T2 - Polymer Gels and Networks
AU - Lee, Wen-Fu
AU - Chen, Chin-Fu
PY - 1998
DA - 1998/12/01
PB - Elsevier
SP - 493-511
IS - 6
VL - 6
SN - 0966-7822
ER -
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@article{1998_Lee,
author = {Wen-Fu Lee and Chin-Fu Chen},
title = {Poly(2-hydroxyethyl methacrylate-co-sulfobetaine)s hydrogels: 3. Synthesis and swelling behaviors of the [2-hydroxyethyl methacrylate-co-N,N′-dimethyl (acrylamido propyl) ammonium propane sulfonate] hydrogels},
journal = {Polymer Gels and Networks},
year = {1998},
volume = {6},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/S0966-7822(99)00002-7},
number = {6},
pages = {493--511},
doi = {10.1016/S0966-7822(99)00002-7}
}
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Lee, Wen Fu, et al. “Poly(2-hydroxyethyl methacrylate-co-sulfobetaine)s hydrogels: 3. Synthesis and swelling behaviors of the [2-hydroxyethyl methacrylate-co-N,N′-dimethyl (acrylamido propyl) ammonium propane sulfonate] hydrogels.” Polymer Gels and Networks, vol. 6, no. 6, Dec. 1998, pp. 493-511. https://doi.org/10.1016/S0966-7822(99)00002-7.