Diastereoselective Halogenation Reactions

Daniel A. Cruz ¹

Victoria Sinka ¹

Juan I Padrón ¹

Molecular Sciences Department, Instituto de Productos Naturales y Agrobiología, Consejo Superior de Investigaciones Científicas (IPNA-CSIC), La Laguna, Spain |

Publication type: Book Chapter

Publication date: 2023-08-10

Elsevier

DOI: 10.1016/b978-0-32-390644-9.00106-2

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Abstract

A review of the last 10 years of diastereoselective halogenation methods is presented. They have been divided by reactions into alkenes, alkynes, and heterocycles. In many of the cases, the use of transition metals is described. In all of them, the mechanistic approach proposed by the authors and justifying the obtained diastereoselection is discussed. A miscellaneous section is also included in which allylic fluorinations, double bond isomerizations, ring expansion, and ring-opening halogenations are discussed.

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Elsevier