Applied Catalysis B: Environmental, volume 272, pages 119006
2D/2D/0D TiO2/C3N4/Ti3C2 MXene composite S-scheme photocatalyst with enhanced CO2 reduction activity
Fei He
,
Fei He
1
,
Bicheng Zhu
1
,
Cheng Bei
,
BEI CHENG
1
,
Jiaguo Yu
2, 3
,
Bei Cheng
4
,
Wojciech Macyk
5, 6, 7
2
5
Faculty of Chemistry
7
30-387 Kraków Poland
|
Publication type: Journal Article
Publication date: 2020-09-01
Journal:
Applied Catalysis B: Environmental
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 22.1
ISSN: 09263373, 18733883
Catalysis
Process Chemistry and Technology
General Environmental Science
Abstract
Herein, two-dimensional (2D) TiO2 mesoporous nanosheets with three to four C3N4 layers grown in situ are employed to design a core–shell 2D/2D van der Waals heterojunction (TiO2/C3N4). Edge-terminated zero-dimensional (0D) Ti3C2 MXene quantum dots (TCQD) are subsequently integrated in the C3N4 surface via electrostatic interactions. The constructed 2D/2D/0D TiO2/C3N4/Ti3C2 composite heterojunction photocatalyst exhibits enhanced CO2 reduction activity compared to TiO2, C3N4, TiO2/C3N4, C3N4/Ti3C2 for CO and CH4 production. A step-scheme (S-scheme) charge transfer mechanism operates for the prepared samples during CO2 reduction, as authenticated by in situ X-ray photoelectron spectroscopy and electron paramagnetic resonance analysis. This study provides a paradigm of a rational structural design for regulating the number and type of heterointerfaces and further insights into the mechanism of multijunction photocatalysts.
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Citations by publishers
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Elsevier
402 publications, 59.12%
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73 publications, 10.74%
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36 publications, 5.29%
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World Scientific
1 publication, 0.15%
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Beilstein-Institut
1 publication, 0.15%
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1 publication, 0.15%
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1 publication, 0.15%
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KeAi Communications Co.
1 publication, 0.15%
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Korean Society of Industrial Engineering Chemistry
1 publication, 0.15%
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Taiwan Institute of Chemical Engineers
1 publication, 0.15%
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1 publication, 0.15%
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Walter de Gruyter
1 publication, 0.15%
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Pleiades Publishing
1 publication, 0.15%
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1 publication, 0.15%
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SPIE
1 publication, 0.15%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
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He F. et al. 2D/2D/0D TiO2/C3N4/Ti3C2 MXene composite S-scheme photocatalyst with enhanced CO2 reduction activity // Applied Catalysis B: Environmental. 2020. Vol. 272. p. 119006.
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He F., He F., Zhu B., Bei C., CHENG B., Yu J., Cheng B., Macyk W. 2D/2D/0D TiO2/C3N4/Ti3C2 MXene composite S-scheme photocatalyst with enhanced CO2 reduction activity // Applied Catalysis B: Environmental. 2020. Vol. 272. p. 119006.
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TY - JOUR
DO - 10.1016/j.apcatb.2020.119006
UR - https://doi.org/10.1016/j.apcatb.2020.119006
TI - 2D/2D/0D TiO2/C3N4/Ti3C2 MXene composite S-scheme photocatalyst with enhanced CO2 reduction activity
T2 - Applied Catalysis B: Environmental
AU - He, Fei
AU - Zhu, Bicheng
AU - Bei, Cheng
AU - Yu, Jiaguo
AU - Cheng, Bei
AU - Macyk, Wojciech
AU - He, Fei
AU - CHENG, BEI
PY - 2020
DA - 2020/09/01 00:00:00
PB - Elsevier
SP - 119006
VL - 272
SN - 0926-3373
SN - 1873-3883
ER -
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@article{2020_He,
author = {Fei He and Bicheng Zhu and Cheng Bei and Jiaguo Yu and Bei Cheng and Wojciech Macyk and Fei He and BEI CHENG},
title = {2D/2D/0D TiO2/C3N4/Ti3C2 MXene composite S-scheme photocatalyst with enhanced CO2 reduction activity},
journal = {Applied Catalysis B: Environmental},
year = {2020},
volume = {272},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.apcatb.2020.119006},
pages = {119006},
doi = {10.1016/j.apcatb.2020.119006}
}