Applied Catalysis B: Environmental, volume 297, pages 120389

Single noble metal atoms doped 2D materials for catalysis

Dongqing Liu 1
Akaash Barbar 2
Tayyaba Najam 2
Muhammad Humza Javed 3
Jun Shen 1
P. Tsiakaras 4, 5
Publication typeJournal Article
Publication date2021-11-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor22.1
ISSN09263373, 18733883
Catalysis
Process Chemistry and Technology
General Environmental Science
Abstract
• Single noble-metal-atoms based on two-dimensional materials (SNA@2DMs) are critically discussed. • Basic understanding of reaction mechanisms and their applications on SNA@2DMs are provided for the main catalytic areas. • For each catalytic area ( electrocatalysis, photocatalysis & thermocatalysis) the major reactions were discussed in details. • Hydrogen evolution reaction, oxygen evolution reaction & oxygen reduction reaction by electrocatalysis . • Water splitting, CO 2 reduction & N 2 fixation by photocatalysis and hydrogenation & CO oxidation by thermocatalysis . Single atoms loaded on two-dimensional materials (SA@2DMs) have been broadly explored recently in the field of catalysis. Compared with conventional supports, 2D materials with large surface areas, unique geometric structure, and electronic properties can boost the catalytic performances of anchored single noble atoms (SNAs). Meanwhile, the monodispersed atoms not only show much higher atom utilization, than their bulk or nanoparticle counterparts, but also provide an alternative reaction pathway with excellent activity and selectivity. However, the combination of a 2D material with single atoms still comes across some challenges, such as low mass loading, difficulty in anchoring the single atoms on the 2D substrates, and difficulty in mass production. In this review, single noble-metal atoms based on two-dimensional materials (SNA@2DM) are critically discussed. First, SNA@2DMs are generally introduced, including their definition, characterization, and their importance and advantages in catalysis. Then, the recent progress in using the SNA@2DMs for the photocatalytic, electrocatalytic, and thermocatalytic reactions is thoroughly reviewed and critically discussed. The superiority and the disadvantages of SNA@2DMs in each catalytic reaction are also considered. Finally, the current challenges and opportunities in the synthesis and applications of SNA@2DM are clearly highlighted.

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Liu D. et al. Single noble metal atoms doped 2D materials for catalysis // Applied Catalysis B: Environmental. 2021. Vol. 297. p. 120389.
GOST all authors (up to 50) Copy
Liu D., Barbar A., Najam T., Javed M. H., Shen J., Tsiakaras P., Cai X. Single noble metal atoms doped 2D materials for catalysis // Applied Catalysis B: Environmental. 2021. Vol. 297. p. 120389.
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RIS Copy
TY - JOUR
DO - 10.1016/j.apcatb.2021.120389
UR - https://doi.org/10.1016/j.apcatb.2021.120389
TI - Single noble metal atoms doped 2D materials for catalysis
T2 - Applied Catalysis B: Environmental
AU - Liu, Dongqing
AU - Barbar, Akaash
AU - Najam, Tayyaba
AU - Javed, Muhammad Humza
AU - Shen, Jun
AU - Tsiakaras, P.
AU - Cai, Xingke
PY - 2021
DA - 2021/11/01 00:00:00
PB - Elsevier
SP - 120389
VL - 297
SN - 0926-3373
SN - 1873-3883
ER -
BibTex
Cite this
BibTex Copy
@article{2021_Liu,
author = {Dongqing Liu and Akaash Barbar and Tayyaba Najam and Muhammad Humza Javed and Jun Shen and P. Tsiakaras and Xingke Cai},
title = {Single noble metal atoms doped 2D materials for catalysis},
journal = {Applied Catalysis B: Environmental},
year = {2021},
volume = {297},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/j.apcatb.2021.120389},
pages = {120389},
doi = {10.1016/j.apcatb.2021.120389}
}
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