Open Access

Catalysis Communications

, volume 59 , pages 222-225

Complementarity of heterogeneous and homogeneous catalysis for oleic acid esterification with trimethylolpropane over ion-exchange resins

Maryna Kuzminska ^{1, 2}

Rénal Backov ²

E.M Gaigneaux ¹

Hide authors affiliations Show authors affiliations: 2 affiliations

Université Catholique de Louvain, Institute of Condensed Matter and Nanosciences—IMCN, Croix du Sud 2, L7.05.17, B-1348 Louvain-la-Neuve, Belgium |

Université de Bordeaux, Centre de Recherche Paul Pascal, CRPP-UPR CNRS 8641, 115 av. du Dr. A. Schweitzer, F-33600 Pessac, France |

Publication type: Journal Article

Publication date: 2015-01-01

Elsevier

Catalysis Communications

scimago Q1

wos Q2

SJR: 0.811

CiteScore: 7.9

Impact factor: 4.3

ISSN: 15667367

DOI: 10.1016/j.catcom.2014.10.033

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General Chemistry

Catalysis

Process Chemistry and Technology

Abstract

This work investigates the effect of Amberlyst 36, Purolite CT482 and Purolite CT275DR on the esterification of oleic acid with trimethylolpropane for production of the triester. The results assess that, while the three resins catalyze heterogeneously the formation of mono- and diesters, the final triester is generated thanks to the acidity of residual oleic acid. This cooperative scenario between heterogeneous and homogeneous catalysis is of first importance, as to complete the reaction over conventional heterogeneous catalyst was not feasible because of the strong steric hindrance of the intermediate product (diester) and the final product (triester).

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GOST Copy

Kuzminska M. et al. Complementarity of heterogeneous and homogeneous catalysis for oleic acid esterification with trimethylolpropane over ion-exchange resins // Catalysis Communications. 2015. Vol. 59. pp. 222-225.

GOST all authors (up to 50) Copy

Kuzminska M., Backov R., Gaigneaux E. Complementarity of heterogeneous and homogeneous catalysis for oleic acid esterification with trimethylolpropane over ion-exchange resins // Catalysis Communications. 2015. Vol. 59. pp. 222-225.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.catcom.2014.10.033

UR - https://doi.org/10.1016/j.catcom.2014.10.033

TI - Complementarity of heterogeneous and homogeneous catalysis for oleic acid esterification with trimethylolpropane over ion-exchange resins

T2 - Catalysis Communications

AU - Kuzminska, Maryna

AU - Backov, Rénal

AU - Gaigneaux, E.M

PY - 2015

DA - 2015/01/01

PB - Elsevier

SP - 222-225

VL - 59

SN - 1566-7367

ER -

BibTex

Cite this

BibTex (up to 50 authors) Copy

@article{2015_Kuzminska,

author = {Maryna Kuzminska and Rénal Backov and E.M Gaigneaux},

title = {Complementarity of heterogeneous and homogeneous catalysis for oleic acid esterification with trimethylolpropane over ion-exchange resins},

journal = {Catalysis Communications},

year = {2015},

volume = {59},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016/j.catcom.2014.10.033},

pages = {222--225},

doi = {10.1016/j.catcom.2014.10.033}

}

Publisher

Elsevier

Journal

Catalysis Communications

scimago Q1

wos Q2

SJR

0.811

CiteScore

7.9

Impact factor

4.3

ISSN

15667367 (Print)