Coordination Chemistry Reviews, volume 438, pages 213889

The role of organonickel reagents in organophosphorus chemistry

Publication typeJournal Article
Publication date2021-07-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor20.6
ISSN00108545
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Organonickel reagents are widely used for the obtaining of the organophosphorus compounds from different phosphorus sources including elemental white phosphorus, phosphorus trichloride and phosphine PH 3 . In particular, new highly efficient and environmentally friendly methods for preparation of organophosphorus compounds bearing phosphorus–carbon bonds have been elaborated using the electrochemically generated organonickel complexes. The synthetic application of the developed techniques towards the formation of wide range of practically important primary, secondary and tertiary organophosphines, with a special focus on unsymmetrical PH phosphines, is disclosed. The mechanistic pathways and the structure of the assumed intermediates formed on some key stages of the overall process are presented for discussion. The elaborated methods operate on the electrochemical techniques with combination of coordination chemistry principles and are considered as an efficient alternative to the more common methods.

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Gafurov Z. N. et al. The role of organonickel reagents in organophosphorus chemistry // Coordination Chemistry Reviews. 2021. Vol. 438. p. 213889.
GOST all authors (up to 50) Copy
Gafurov Z. N., Kagilev A. A., Kantyukov A. O., Sinyashin O. G., Yakhvarov D. The role of organonickel reagents in organophosphorus chemistry // Coordination Chemistry Reviews. 2021. Vol. 438. p. 213889.
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RIS Copy
TY - JOUR
DO - 10.1016/j.ccr.2021.213889
UR - https://doi.org/10.1016%2Fj.ccr.2021.213889
TI - The role of organonickel reagents in organophosphorus chemistry
T2 - Coordination Chemistry Reviews
AU - Gafurov, Zufar N
AU - Kagilev, Alexey A
AU - Kantyukov, Artyom O
AU - Sinyashin, Oleg G.
AU - Yakhvarov, Dmitry
PY - 2021
DA - 2021/07/01 00:00:00
PB - Elsevier
SP - 213889
VL - 438
SN - 0010-8545
ER -
BibTex
Cite this
BibTex Copy
@article{2021_Gafurov,
author = {Zufar N Gafurov and Alexey A Kagilev and Artyom O Kantyukov and Oleg G. Sinyashin and Dmitry Yakhvarov},
title = {The role of organonickel reagents in organophosphorus chemistry},
journal = {Coordination Chemistry Reviews},
year = {2021},
volume = {438},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016%2Fj.ccr.2021.213889},
pages = {213889},
doi = {10.1016/j.ccr.2021.213889}
}
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