Coordination Chemistry Reviews, volume 442, pages 213986

Electrochemical methods for synthesis and in situ generation of organometallic compounds

Gafurov Zufar N ¹

Kantyukov Artyom O ^{1, 2}

Kagilev Alexey A ^{1, 2}

Sinyashin Oleg G. ¹

Yakhvarov Dmitry ^{1, 2}

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Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Arbuzov str. 8, 420088 Kazan, Russian Federation

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kremlyovskaya str. 18, 420008 Kazan, Russian Federation |

Publication type: Journal Article

Publication date: 2021-09-01

Elsevier

Journal: Coordination Chemistry Reviews

Quartile SCImago

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Impact factor: 20.6

ISSN: 00108545

DOI: 10.1016/j.ccr.2021.213986

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Materials Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

• Electrochemical methods have been used for the preparation of organometallic compounds. • Main electrochemical synthetic and analytical methods and types of the electrochemical cells are described. • The electrochemically generated high-reactive organometallic species have been used in situ as the reagents for the synthesis of organic and organoelement compounds. • The application of in situ spectroelectrochemical methods for elucidating of the nature of organometallic intermediates formed in the electrochemical process and their application for the activation of organometallics for catalytical purposes are discussed. The electrochemical methods have a huge synthetic potential in both academia and industry. However, the implementation of electrochemistry for the synthesis of organometallic compounds is presented limitedly, while the sustainability and greenness of the electrochemical protocols allow considering them as a very promising and intriguing approach. This review summarizes the most important and practically useful advances in the electrochemistry of organometallics with the emphases on the direct electrochemical synthesis of organometallic derivatives by the formation of a carbon–metal bond, electrosynthesis of organic compounds mediated by in situ generated organometallics as well as cyclic voltammetry and related techniques, applied for analysis and preparation of organometallic compounds.

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Citations by journals

	1 2
Journal of Electroanalytical Chemistry	Journal of Electroanalytical Chemistry, 2, 6.25% Journal of Electroanalytical Chemistry 2 publications, 6.25%
Angewandte Chemie	Angewandte Chemie, 2, 6.25% Angewandte Chemie 2 publications, 6.25%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 2, 6.25% Angewandte Chemie - International Edition 2 publications, 6.25%
ACS Catalysis	ACS Catalysis, 2, 6.25% ACS Catalysis 2 publications, 6.25%
Journal of Physical Chemistry C	Journal of Physical Chemistry C, 1, 3.13% Journal of Physical Chemistry C 1 publication, 3.13%
Russian Journal of Electrochemistry	Russian Journal of Electrochemistry, 1, 3.13% Russian Journal of Electrochemistry 1 publication, 3.13%
Molecules	Molecules, 1, 3.13% Molecules 1 publication, 3.13%
Journal of Organometallic Chemistry	Journal of Organometallic Chemistry, 1, 3.13% Journal of Organometallic Chemistry 1 publication, 3.13%
Science Bulletin	Science Bulletin, 1, 3.13% Science Bulletin 1 publication, 3.13%
Trends in Environmental Analytical Chemistry	Trends in Environmental Analytical Chemistry, 1, 3.13% Trends in Environmental Analytical Chemistry 1 publication, 3.13%
Journal of Structural Chemistry	Journal of Structural Chemistry, 1, 3.13% Journal of Structural Chemistry 1 publication, 3.13%
Russian Journal of General Chemistry	Russian Journal of General Chemistry, 1, 3.13% Russian Journal of General Chemistry 1 publication, 3.13%
Inorganic Chemistry Frontiers	Inorganic Chemistry Frontiers, 1, 3.13% Inorganic Chemistry Frontiers 1 publication, 3.13%
Journal of Organic Chemistry	Journal of Organic Chemistry, 1, 3.13% Journal of Organic Chemistry 1 publication, 3.13%
Chemical Science	Chemical Science, 1, 3.13% Chemical Science 1 publication, 3.13%
CrystEngComm	CrystEngComm, 1, 3.13% CrystEngComm 1 publication, 3.13%
Asian Journal of Organic Chemistry	Asian Journal of Organic Chemistry, 1, 3.13% Asian Journal of Organic Chemistry 1 publication, 3.13%
Advanced Materials	Advanced Materials, 1, 3.13% Advanced Materials 1 publication, 3.13%
Inorganic Chemistry Communication	Inorganic Chemistry Communication, 1, 3.13% Inorganic Chemistry Communication 1 publication, 3.13%
Journal of Solid State Electrochemistry	Journal of Solid State Electrochemistry, 1, 3.13% Journal of Solid State Electrochemistry 1 publication, 3.13%
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 1, 3.13% Journal of the Electrochemical Society 1 publication, 3.13%
Inorganic Chemistry	Inorganic Chemistry, 1, 3.13% Inorganic Chemistry 1 publication, 3.13%
New Journal of Chemistry	New Journal of Chemistry, 1, 3.13% New Journal of Chemistry 1 publication, 3.13%
Analytical Chemistry	Analytical Chemistry, 1, 3.13% Analytical Chemistry 1 publication, 3.13%
	1 2

Citations by publishers

	1 2 3 4 5 6
American Chemical Society (ACS)	American Chemical Society (ACS), 6, 18.75% American Chemical Society (ACS) 6 publications, 18.75%
Elsevier	Elsevier, 6, 18.75% Elsevier 6 publications, 18.75%
Wiley	Wiley, 6, 18.75% Wiley 6 publications, 18.75%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 4, 12.5% Royal Society of Chemistry (RSC) 4 publications, 12.5%
Pleiades Publishing	Pleiades Publishing, 3, 9.38% Pleiades Publishing 3 publications, 9.38%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 3.13% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 3.13%
Springer Nature	Springer Nature, 1, 3.13% Springer Nature 1 publication, 3.13%
The Electrochemical Society	The Electrochemical Society, 1, 3.13% The Electrochemical Society 1 publication, 3.13%
	1 2 3 4 5 6

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Gafurov Z. N. et al. Electrochemical methods for synthesis and in situ generation of organometallic compounds // Coordination Chemistry Reviews. 2021. Vol. 442. p. 213986.

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Gafurov Z. N., Kantyukov A. O., Kagilev A. A., Sinyashin O. G., Yakhvarov D. Electrochemical methods for synthesis and in situ generation of organometallic compounds // Coordination Chemistry Reviews. 2021. Vol. 442. p. 213986.

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RIS Copy

TY - JOUR

DO - 10.1016/j.ccr.2021.213986

UR - https://doi.org/10.1016%2Fj.ccr.2021.213986

TI - Electrochemical methods for synthesis and in situ generation of organometallic compounds

T2 - Coordination Chemistry Reviews

AU - Gafurov, Zufar N

AU - Kantyukov, Artyom O

AU - Kagilev, Alexey A

AU - Sinyashin, Oleg G.

AU - Yakhvarov, Dmitry

PY - 2021

DA - 2021/09/01 00:00:00

PB - Elsevier

SP - 213986

VL - 442

SN - 0010-8545

ER -

BibTex

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BibTex Copy

@article{2021_Gafurov,

author = {Zufar N Gafurov and Artyom O Kantyukov and Alexey A Kagilev and Oleg G. Sinyashin and Dmitry Yakhvarov},

title = {Electrochemical methods for synthesis and in situ generation of organometallic compounds},

journal = {Coordination Chemistry Reviews},

year = {2021},

volume = {442},

publisher = {Elsevier},

month = {sep},

url = {https://doi.org/10.1016%2Fj.ccr.2021.213986},

pages = {213986},

doi = {10.1016/j.ccr.2021.213986}

}

Found error?

Publisher

Elsevier

Journal

Coordination Chemistry Reviews

Quartile SCImago

Quartile WOS

Impact factor

20.6

ISSN

00108545 (Print)

Labs

Laboratory of Organometallic and Coordination Compounds

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