Ceramics International, volume 50, issue 18, pages 32755-32770

Erosion behaviors and mechanisms of Ti3AlC2 material under arc discharge in various mixed atmospheres

Hao Zhao 1, 2
Xin Zhao 3
Zhenzhen Hui 1, 2
Xuchun Wang 1, 2
Haofei Shi 2
Huang Xiaochen 4
1
 
Anhui Province Quartz Sand Purification and Photovoltaic Glass Engineering Research Center, Bengbu, Anhui, 233030, China
4
 
School of Material and Chemical Engineering, Bengbu University, Bengbu, Anhui, 233030, China
Publication typeJournal Article
Publication date2024-09-01
scimago Q1
SJR0.938
CiteScore9.4
Impact factor5.1
ISSN02728842, 18733956
Abstract
The present study establishes an experimental platform for investigating arc erosion and explores the erosion characteristics of Ti3AlC2 material under a voltage of 10 kV in SF6/N2, SF6/CO2, and N2/CO2 environments. Our findings reveal that the arc energy and duration exhibit a gradual increase in the sequence of SF6/N2, SF6/CO2, and N2/CO2, while the breakdown strength decreases. Scanning electron microscopy (SEM) and a three-dimensional laser confocal microscope were employed to observe uneven erosion morphology. Additionally, high-speed camera footage captures the arc bending and drifting phenomenon caused by Rayleigh-Taylor instability between the arc and gas. X-ray diffraction (XRD), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS) analysis were utilized to characterize the composition of eroded surfaces. Erosion models were proposed for each mixed atmosphere along with comprehensive discussions on their underlying mechanisms. This work expands the application scope of MAX phase materials while providing a theoretical foundation for designing electrical contact materials.

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