Colloids and Surfaces A: Physicochemical and Engineering Aspects, volume 510, pages 33-42
Supramolecular systems based on gemini surfactants for enhancing solubility of spectral probes and drugs in aqueous solution
Publication type: Journal Article
Publication date: 2016-12-01
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 5.2
ISSN: 09277757, 18734359
Colloid and Surface Chemistry
Abstract
Herein, novel dicationic surfactants bearing morpholinium moieties in polar group, 14-s-14 Mor (s = 4, 6, 8, 10) are synthesized, and their aggregation behavior is studied and compared with reference surfactants, single-head morpholinium surfactant Mor-14, typical gemini with ammonium head group and dicationic surfactants with heterocyclic polar fragment. Geminis studied are found to exhibit superior solubilization capacity toward a pH indicator thymolphthalein and an inflammatory drug indomethacin, exceeding that of reference amphiphiles. The solubility of the probes is contributed by multifactor mechanism involving the solubilization in nonpolar core of micelles and periphery electrostatic interaction between micellar surface charge and ionic moieties of the drug. Mutual influence of the components occurs on their properties, including pKa shift of ionogenic groups of a guest molecule and decrease in critical micelle concentration of geminis.
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Mirgorodskaya A. B. et al. Supramolecular systems based on gemini surfactants for enhancing solubility of spectral probes and drugs in aqueous solution // Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2016. Vol. 510. pp. 33-42.
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Mirgorodskaya A. B., Ya Zakharova L., Khairutdinova E. I., Lukashenko S. S., Sinyashin O. G. Supramolecular systems based on gemini surfactants for enhancing solubility of spectral probes and drugs in aqueous solution // Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2016. Vol. 510. pp. 33-42.
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TY - JOUR
DO - 10.1016/j.colsurfa.2016.07.065
UR - https://doi.org/10.1016%2Fj.colsurfa.2016.07.065
TI - Supramolecular systems based on gemini surfactants for enhancing solubility of spectral probes and drugs in aqueous solution
T2 - Colloids and Surfaces A: Physicochemical and Engineering Aspects
AU - Mirgorodskaya, A B
AU - Ya Zakharova, L
AU - Khairutdinova, E I
AU - Lukashenko, Svetlana S
AU - Sinyashin, Oleg G.
PY - 2016
DA - 2016/12/01 00:00:00
PB - Elsevier
SP - 33-42
VL - 510
SN - 0927-7757
SN - 1873-4359
ER -
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@article{2016_Mirgorodskaya,
author = {A B Mirgorodskaya and L Ya Zakharova and E I Khairutdinova and Svetlana S Lukashenko and Oleg G. Sinyashin},
title = {Supramolecular systems based on gemini surfactants for enhancing solubility of spectral probes and drugs in aqueous solution},
journal = {Colloids and Surfaces A: Physicochemical and Engineering Aspects},
year = {2016},
volume = {510},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016%2Fj.colsurfa.2016.07.065},
pages = {33--42},
doi = {10.1016/j.colsurfa.2016.07.065}
}
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