Corrosion Science

, volume 162 , pages 108221

Probing the correlation between phase evolution and growth kinetics in the oxide layers of tungsten using Raman spectroscopy and EBSD

George Fulton ¹

Artem Lunev ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

United Kingdom Atomic Energy Authority (UKAEA), Culham Science Centre, Abingdon, Oxfordshire OX14 3DB, United Kingdom |

Publication type: Journal Article

Publication date: 2020-01-01

Elsevier

Corrosion Science

scimago Q1

wos Q1

SJR: 2.189

CiteScore: 14.1

Impact factor: 8.5

ISSN: 0010938X, 18790496

DOI: 10.1016/j.corsci.2019.108221

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General Chemistry

General Chemical Engineering

General Materials Science

Abstract

Tungsten, a plasma-facing material for future fusion reactors, may be exposed to air during abnormal operation or accidents. Only limited information is available on the evolution of related oxide phases. This work addresses the effect of substrate orientation on structural variations of tungsten oxides. Annealing experiments in an argon-oxygen atmosphere have been conducted at T = 400 {\deg}C under varying oxygen partial pressure and oxidation time. A combination of EBSD, Raman spectroscopy and confocal microscopy shows preferential oxidation initially on {111} base material planes. The oxide scale changes its phase composition dynamically, influencing the kinetics of its growth.

Found

1 citation

Medvedev Dmitry

🤝

DSc in Chemistry

192 publications, 5 796 citations, 106 reviews

h-index: 43

Institute of High Temperature Electrochemistry of the Ural Branch of the Russian Academy of Sciences

Ural Federal University

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Fulton G., Lunev A. Probing the correlation between phase evolution and growth kinetics in the oxide layers of tungsten using Raman spectroscopy and EBSD // Corrosion Science. 2020. Vol. 162. p. 108221.

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RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.corsci.2019.108221

UR - https://doi.org/10.1016/j.corsci.2019.108221

TI - Probing the correlation between phase evolution and growth kinetics in the oxide layers of tungsten using Raman spectroscopy and EBSD

T2 - Corrosion Science

AU - Fulton, George

AU - Lunev, Artem

PY - 2020

DA - 2020/01/01

PB - Elsevier

SP - 108221

VL - 162

SN - 0010-938X

SN - 1879-0496

ER -

BibTex

Cite this

BibTex (up to 50 authors) Copy

@article{2020_Fulton,

author = {George Fulton and Artem Lunev},

title = {Probing the correlation between phase evolution and growth kinetics in the oxide layers of tungsten using Raman spectroscopy and EBSD},

journal = {Corrosion Science},

year = {2020},

volume = {162},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016/j.corsci.2019.108221},

pages = {108221},

doi = {10.1016/j.corsci.2019.108221}

}

Publisher

Elsevier

Journal

Corrosion Science

scimago Q1

wos Q1

SJR

2.189

CiteScore

14.1

Impact factor

8.5

ISSN

0010938X (Print)

18790496