Energy Procedia, volume 142, pages 3667-3674
Numerical and experimental study of the flow-by cell for Vanadium Redox Batteries
Publication type: Journal Article
Publication date: 2017-12-01
General Medicine
Abstract
A mathematical model for vanadium redox batteries (VRBs) is considered. The model has been tuned using experimental data obtained for a single cell with flow-by design. Mass transfer limitations have been determined from experimental data, and a new correlation for mass transfer constant is proposed. Self-discharge of the battery resulting from crossover of vanadium ions through membrane is taken into account by the model as well. It is shown that Fick’s law for diffusion describes crossover rather well. The crossover has a large impact on the battery voltage during discharge, but can be neglected during charge due to mutual compensation of diffusion and migration fluxes. Good agreement (with average error less than 7 %) between the experimental and modelled polarization and charge-discharge curves is observed in the whole current density region.
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Citations by publishers
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Elsevier
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1 publication, 7.69%
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IEEE
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1 publication, 7.69%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Pugach M. et al. Numerical and experimental study of the flow-by cell for Vanadium Redox Batteries // Energy Procedia. 2017. Vol. 142. pp. 3667-3674.
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Pugach M., Kondratenko M., Briola S., Bischi A. Numerical and experimental study of the flow-by cell for Vanadium Redox Batteries // Energy Procedia. 2017. Vol. 142. pp. 3667-3674.
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TY - JOUR
DO - 10.1016/j.egypro.2017.12.260
UR - https://doi.org/10.1016%2Fj.egypro.2017.12.260
TI - Numerical and experimental study of the flow-by cell for Vanadium Redox Batteries
T2 - Energy Procedia
AU - Pugach, M.
AU - Kondratenko, M
AU - Briola, S
AU - Bischi, Aldo
PY - 2017
DA - 2017/12/01 00:00:00
PB - Elsevier
SP - 3667-3674
VL - 142
SN - 1876-6102
ER -
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@article{2017_Pugach,
author = {M. Pugach and M Kondratenko and S Briola and Aldo Bischi},
title = {Numerical and experimental study of the flow-by cell for Vanadium Redox Batteries},
journal = {Energy Procedia},
year = {2017},
volume = {142},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016%2Fj.egypro.2017.12.260},
pages = {3667--3674},
doi = {10.1016/j.egypro.2017.12.260}
}
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