Electrochimica Acta, volume 241, pages 362-369

Role of Electrode Reaction Kinetics in Self-Ordering of Porous Anodic Alumina

Roslyakov I. V. ¹

Gordeeva Elena O ²

Napolskii Kirill S. ¹

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Department of Materials Science, Lomonosov Moscow State University, Moscow 119991, Russia |

Department of Materials Science, Lomonosov Moscow State University, Moscow, 119991 (Russia) |

Publication type: Journal Article

Publication date: 2017-07-01

Elsevier

Journal: Electrochimica Acta

Quartile SCImago

Quartile WOS

Impact factor: 6.6

ISSN: 00134686

DOI: 10.1016/j.electacta.2017.04.140

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General Chemical Engineering

Electrochemistry

Abstract

Porous anodic aluminium oxide with long-range ordered structure is of high practical importance in modern materials science and nanotechnology owing to its wide applications as membranes or templates for various nanostructures. However, the fundamental reason of self-organized growth of honeycomb-like porous anodic alumina films solely within a narrow region of processing conditions remains unknown. Here we show that the formation of the long-range ordered porous structure occurs only when anodization rate is limited by migration in barrier layer, which separates metal and electrolyte, or by diffusion in pores, whereas the mixed control of anodic oxidation process leads to disordered porous structures. The universality of this conclusion is experimentally confirmed for anodization in oxalic and sulfuric acid solutions, which are the most versatile anodizing electrolytes. The predictive power of the suggested model is demonstrated for anodic oxidation of aluminium in 2 M sulfuric acid electrolyte, in which mild and hard anodization regimes leading to the formation of highly ordered porous structures are developed. It allows one to intentionally choose proper anodization conditions instead of simple empirical search that has been used so far.

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Materials and Design	Materials and Design, 1, 1.52% Materials and Design 1 publication, 1.52%
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Optical Materials	Optical Materials, 1, 1.52% Optical Materials 1 publication, 1.52%
Journal of Applied Crystallography	Journal of Applied Crystallography, 1, 1.52% Journal of Applied Crystallography 1 publication, 1.52%
Materials Advances	Materials Advances, 1, 1.52% Materials Advances 1 publication, 1.52%
Molecules	Molecules, 1, 1.52% Molecules 1 publication, 1.52%
Frontiers in Physics	Frontiers in Physics, 1, 1.52% Frontiers in Physics 1 publication, 1.52%
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Citations by publishers

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Elsevier	Elsevier, 24, 36.36% Elsevier 24 publications, 36.36%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 8, 12.12% Multidisciplinary Digital Publishing Institute (MDPI) 8 publications, 12.12%
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IOP Publishing	IOP Publishing, 3, 4.55% IOP Publishing 3 publications, 4.55%
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Springer Nature	Springer Nature, 2, 3.03% Springer Nature 2 publications, 3.03%
American Physical Society (APS)	American Physical Society (APS), 1, 1.52% American Physical Society (APS) 1 publication, 1.52%
International Union of Crystallography (IUCr)	International Union of Crystallography (IUCr), 1, 1.52% International Union of Crystallography (IUCr) 1 publication, 1.52%
Frontiers Media S.A.	Frontiers Media S.A., 1, 1.52% Frontiers Media S.A. 1 publication, 1.52%
King Saud University	King Saud University, 1, 1.52% King Saud University 1 publication, 1.52%
Japan Institute of Light Metals	Japan Institute of Light Metals, 1, 1.52% Japan Institute of Light Metals 1 publication, 1.52%
Wiley	Wiley, 1, 1.52% Wiley 1 publication, 1.52%
Taylor & Francis	Taylor & Francis, 1, 1.52% Taylor & Francis 1 publication, 1.52%
Hindawi Limited	Hindawi Limited, 1, 1.52% Hindawi Limited 1 publication, 1.52%
National Academy of Sciences of Ukraine (Co. LTD Ukrinformnauka) (Publications)	National Academy of Sciences of Ukraine (Co. LTD Ukrinformnauka) (Publications), 1, 1.52% National Academy of Sciences of Ukraine (Co. LTD Ukrinformnauka) (Publications) 1 publication, 1.52%
	5 10 15 20 25

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Roslyakov I. V., Gordeeva E. O., Napolskii K. S. Role of Electrode Reaction Kinetics in Self-Ordering of Porous Anodic Alumina // Electrochimica Acta. 2017. Vol. 241. pp. 362-369.

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Roslyakov I. V., Gordeeva E. O., Napolskii K. S. Role of Electrode Reaction Kinetics in Self-Ordering of Porous Anodic Alumina // Electrochimica Acta. 2017. Vol. 241. pp. 362-369.

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RIS Copy

TY - JOUR

DO - 10.1016/j.electacta.2017.04.140

UR - https://doi.org/10.1016%2Fj.electacta.2017.04.140

TI - Role of Electrode Reaction Kinetics in Self-Ordering of Porous Anodic Alumina

T2 - Electrochimica Acta

AU - Gordeeva, Elena O

AU - Roslyakov, I. V.

AU - Napolskii, Kirill S.

PY - 2017

DA - 2017/07/01 00:00:00

PB - Elsevier

SP - 362-369

VL - 241

SN - 0013-4686

ER -

BibTex

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BibTex Copy

@article{2017_Roslyakov,

author = {Elena O Gordeeva and I. V. Roslyakov and Kirill S. Napolskii},

title = {Role of Electrode Reaction Kinetics in Self-Ordering of Porous Anodic Alumina},

journal = {Electrochimica Acta},

year = {2017},

volume = {241},

publisher = {Elsevier},

month = {jul},

url = {https://doi.org/10.1016%2Fj.electacta.2017.04.140},

pages = {362--369},

doi = {10.1016/j.electacta.2017.04.140}

}

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Publisher

Elsevier

Journal

Electrochimica Acta

Quartile SCImago

Quartile WOS

Impact factor

6.6

ISSN

00134686 (Print)

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Electrochemical Nanostructuring Group

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