Single-crystal rare earths manganites La1−x−yBixAyMnαO3±β (A = Ba, Pb): Crystal structure, composition, and Mn ions valence state. X-ray diffraction and XPS study
A.T. Kozakov
1
,
Andrei Kochur
2
,
L. Reznichenko
1
,
L A Shilkina
1
,
A V Pavlenko
1
,
A.V. Nikolskii
1
,
K A Googlev
1
,
V. G. Smotrakov
1
Publication type: Journal Article
Publication date: 2013-02-09
scimago Q2
wos Q3
SJR: 0.601
CiteScore: 3.6
Impact factor: 1.5
ISSN: 03682048, 18732526
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
Spectroscopy
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Radiation
Abstract
Abstract Single crystals of La1−xBixMnαO3±β and La1−x−yBixAyMnαO3±β (A = Ba, Pb) are grown, their crystal and electron structure is studied. Relative Mn3+/Mn4+ abundance in each single crystal is determined via fitting experimental Mn2p-spectra with weighted superposition of theoretical spectra of tri- and quadrivalent Mn, and, for barium-free samples, from energy splitting of the Mn3s-spectra components. Strong heterogeneousness of the crystals both in elemental composition and crystal structure is discovered. It is shown that the heterogeneousness displays itself in various oxygenic environments around Mn atoms which give rise to the appearance of Mn4+ ions. A simple model is proposed that allows understanding the nature of the appearance of Mn4+ ions in single crystals of lanthanum–bismuth manganites.
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Kozakov A. et al. Single-crystal rare earths manganites La1−x−yBixAyMnαO3±β (A = Ba, Pb): Crystal structure, composition, and Mn ions valence state. X-ray diffraction and XPS study // Journal of Electron Spectroscopy and Related Phenomena. 2013. Vol. 186. pp. 14-24.
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Kozakov A., Kochur A., Reznichenko L., Shilkina L. A., Pavlenko A. V., Nikolskii A., Googlev K. A., Smotrakov V. G. Single-crystal rare earths manganites La1−x−yBixAyMnαO3±β (A = Ba, Pb): Crystal structure, composition, and Mn ions valence state. X-ray diffraction and XPS study // Journal of Electron Spectroscopy and Related Phenomena. 2013. Vol. 186. pp. 14-24.
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TY - JOUR
DO - 10.1016/j.elspec.2013.01.016
UR - https://doi.org/10.1016/j.elspec.2013.01.016
TI - Single-crystal rare earths manganites La1−x−yBixAyMnαO3±β (A = Ba, Pb): Crystal structure, composition, and Mn ions valence state. X-ray diffraction and XPS study
T2 - Journal of Electron Spectroscopy and Related Phenomena
AU - Kozakov, A.T.
AU - Kochur, Andrei
AU - Reznichenko, L.
AU - Shilkina, L A
AU - Pavlenko, A V
AU - Nikolskii, A.V.
AU - Googlev, K A
AU - Smotrakov, V. G.
PY - 2013
DA - 2013/02/09
PB - Elsevier
SP - 14-24
VL - 186
SN - 0368-2048
SN - 1873-2526
ER -
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BibTex (up to 50 authors)
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@article{2013_Kozakov,
author = {A.T. Kozakov and Andrei Kochur and L. Reznichenko and L A Shilkina and A V Pavlenko and A.V. Nikolskii and K A Googlev and V. G. Smotrakov},
title = {Single-crystal rare earths manganites La1−x−yBixAyMnαO3±β (A = Ba, Pb): Crystal structure, composition, and Mn ions valence state. X-ray diffraction and XPS study},
journal = {Journal of Electron Spectroscopy and Related Phenomena},
year = {2013},
volume = {186},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.elspec.2013.01.016},
pages = {14--24},
doi = {10.1016/j.elspec.2013.01.016}
}