Open Access
Energetic Materials Frontiers, volume 2, issue 2, pages 131-138
Combination of 1,2,3-triazole and 1,2,4-triazole frameworks for new high-energy and low-sensitivity compounds
Publication type: Journal Article
Publication date: 2021-06-02
Journal:
Energetic Materials Frontiers
Quartile SCImago
Q1
Quartile WOS
—
Impact factor: —
ISSN: 26666472
General Medicine
Abstract
In this study, a series of energetic compounds based on C–C linked 1,2,3-triazole and 1,2,4-triazole were synthesized and characterized, i.e. , 5-(5-nitro-2H-1,2,3-triazole-4-yl)-4H-1,2,4-triazole-3,4-diamine (compound 1 ), N-(3-amino-5-(5-nitro-2H-1,2,3-triazole-4-yl)-4H-1,2,4-triazole-4-yl) nitramide (compound 4 ), and their energetic salts (compounds 2 , 3 , 5 , and 6 ). The structures of compounds 1 , 2, and 4 were determined by X-ray diffraction. All the new compounds feature acceptable thermal stability ( T dec = 185–266 °C), with thermal decomposition temperature higher than that of RDX ( T dec = 204 °C) except for compound 6 ( T dec = 185 °C). Moreover, the detonation velocities of compounds 5 and 6 are 9200 m·s −1 and 9024 m·s −1 , respectively, which are higher than that of RDX ( D = 8795 m·s −1 ). Furthermore, the new compounds show low mechanical sensitivity (IS = 20 J, FS = 240 N) compared to RDX (IS = 7.4 J, FS = 120 N). These results will help to accelerate the development of new high-energy density materials. The energetic compounds with high thermal stability and energetic performances were synthesized based on the combination of 1,2,3-triazole and 1,2,4-triazole.
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Yao W. et al. Combination of 1,2,3-triazole and 1,2,4-triazole frameworks for new high-energy and low-sensitivity compounds // Energetic Materials Frontiers. 2021. Vol. 2. No. 2. pp. 131-138.
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Yao W., Xue Y., Lei Q., YANG H., Cheng G. Combination of 1,2,3-triazole and 1,2,4-triazole frameworks for new high-energy and low-sensitivity compounds // Energetic Materials Frontiers. 2021. Vol. 2. No. 2. pp. 131-138.
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TY - JOUR
DO - 10.1016/j.enmf.2021.05.002
UR - https://doi.org/10.1016/j.enmf.2021.05.002
TI - Combination of 1,2,3-triazole and 1,2,4-triazole frameworks for new high-energy and low-sensitivity compounds
T2 - Energetic Materials Frontiers
AU - Yao, Wenjing
AU - Xue, Yubing
AU - Lei, Qian
AU - YANG, HONGWEI
AU - Cheng, Guangbin
PY - 2021
DA - 2021/06/02 00:00:00
PB - Elsevier
SP - 131-138
IS - 2
VL - 2
SN - 2666-6472
ER -
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@article{2021_Yao,
author = {Wenjing Yao and Yubing Xue and Qian Lei and HONGWEI YANG and Guangbin Cheng},
title = {Combination of 1,2,3-triazole and 1,2,4-triazole frameworks for new high-energy and low-sensitivity compounds},
journal = {Energetic Materials Frontiers},
year = {2021},
volume = {2},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.enmf.2021.05.002},
number = {2},
pages = {131--138},
doi = {10.1016/j.enmf.2021.05.002}
}
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MLA
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Yao, Wenjing, et al. “Combination of 1,2,3-triazole and 1,2,4-triazole frameworks for new high-energy and low-sensitivity compounds.” Energetic Materials Frontiers, vol. 2, no. 2, Jun. 2021, pp. 131-138. https://doi.org/10.1016/j.enmf.2021.05.002.