Environmental Research, volume 217, pages 114825

Enhanced photodegradation of tetracycline in wastewater and conversion of CO2 by solar light assisted ZnO/g-C3N4

Thi Huong Pham 1
Man Hieu Tran 1
Chu Thi Thu Hien 2
Yusik Myung 1
Sung Hoon Jung 1
Mitesh G Mapari 1
Taeyoung Kim 1
2
 
Department of Chemistry, Faculty of Building Materials, Ha Noi University of Civil Engineering (HUCE), Giai Phong, Hai Ba Trung, Hanoi, 10000, Viet Nam
Publication typeJournal Article
Publication date2023-01-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor8.3
ISSN00139351, 10960953
Biochemistry
General Environmental Science
Abstract
Synthesized graphitic carbon nitride-based (CN) heterojunction photocatalysts are considered as a promising material for photodegradation of organic compounds and CO2 conversion. In this work, ZnO-loaded g-C3N4 (ZnO/CN) heterojunction photocatalyst was investigated for the enhanced photooxidation of tetracycline (TC) and CO2 conversion . After modification, the photocatalysts showed an improvement in the light absorption range and the photogenerated separation rate of electron/hole due to the heterojunction structure of ZnO/CN. The degradation rate of TC was found to be 92.6% within 60 min, while CO production rate was 7.68 μmol/g/h. The rate constants of TC by using ZnO/CN were 0.0812, 0.0539, 0.0336, 0.0249, and 0.0185 min-1, corresponding to the TC level of 1, 10, 30, 50, and 100 mg/L, respectively. The photodegradation rate of TC by ZnO/CN was 5 times higher than that of CN, demonstrating the advantage of heterojunction photocatalyst. The modified ZnO/CN exhibited superior degradation performance of TC and higher CO2 conversion rate than those of unmodified CN. It also exhibited high stability with 82% removal efficiency of TC at the 6th run and the CO2 conversion rate of 71% after reused 5 times. The heterojunction ZnO/CN can be utilized as an efficient material for various photocatalytic applications.

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Pham T. H. et al. Enhanced photodegradation of tetracycline in wastewater and conversion of CO2 by solar light assisted ZnO/g-C3N4 // Environmental Research. 2023. Vol. 217. p. 114825.
GOST all authors (up to 50) Copy
Pham T. H., Tran M. H., Hien C. T. T., Myung Y., Jung S. H., Mapari M. G., Kim T. Enhanced photodegradation of tetracycline in wastewater and conversion of CO2 by solar light assisted ZnO/g-C3N4 // Environmental Research. 2023. Vol. 217. p. 114825.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.envres.2022.114825
UR - https://doi.org/10.1016/j.envres.2022.114825
TI - Enhanced photodegradation of tetracycline in wastewater and conversion of CO2 by solar light assisted ZnO/g-C3N4
T2 - Environmental Research
AU - Pham, Thi Huong
AU - Tran, Man Hieu
AU - Hien, Chu Thi Thu
AU - Myung, Yusik
AU - Jung, Sung Hoon
AU - Mapari, Mitesh G
AU - Kim, Taeyoung
PY - 2023
DA - 2023/01/01 00:00:00
PB - Elsevier
SP - 114825
VL - 217
SN - 0013-9351
SN - 1096-0953
ER -
BibTex
Cite this
BibTex Copy
@article{2023_Pham,
author = {Thi Huong Pham and Man Hieu Tran and Chu Thi Thu Hien and Yusik Myung and Sung Hoon Jung and Mitesh G Mapari and Taeyoung Kim},
title = {Enhanced photodegradation of tetracycline in wastewater and conversion of CO2 by solar light assisted ZnO/g-C3N4},
journal = {Environmental Research},
year = {2023},
volume = {217},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.envres.2022.114825},
pages = {114825},
doi = {10.1016/j.envres.2022.114825}
}
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