Inorganica Chimica Acta, volume 477, pages 277-283
Synthesis and stability studies of derivatives of the 2-sulfanyl-closo-decaborate anion [2-B10H9SH]2−
Matveev E Yu
2
,
Turyshev E S
3
,
Polyakova Irina V.
1
,
Nichugovskiy A I
2
,
Zhizhin Konstantin Yu.
2, 4
,
Kuznetsov N. T.
1
Publication type: Journal Article
Publication date: 2018-05-01
Journal:
Inorganica Chimica Acta
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 2.8
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
By acylation of [2-B10H9SH]2− (1) with trifluoroacetic anhydride was synthesized the anion [B10H9SCOCF3]2− (2). The alkaline and acid hydrolysis of the [B10H9S(CH2COOEt)2]− anion leading to the formation of [B10H9S(CH2COOH)2]− (3) gave evidence of high stability of sulfonium derivatives. While in phosphate buffer at pH = 5 the semi-hydrolysis time of thioesters [B10H9SCOCH3]2−, [B10H9SCOCF3]2− (2), and [B10H9SCOC6H5]2− were 600, 17 and 168 h. The substituted closo-decaborates were characterized by IR and NMR (1H, 11B, 13C) spectroscopy. The crystal structures of (Bu4N)3[B10H9(CH2COO)2H]2 (3) and Cs5(Bu4N)[B10H9SC(O)CF3]3 (2a) were determined by X-ray diffraction. In structure 3, anions were associated via strong O H⋯O hydrogen bonds into centrosymmetric hexacharged tetramers. In structure 2a, anions formed the environment of all cesium cations and chelated one of them due to Cs O and Cs HB bonds.
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- We do not take into account publications that without a DOI.
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Kubasov A. S. et al. Synthesis and stability studies of derivatives of the 2-sulfanyl-closo-decaborate anion [2-B10H9SH]2− // Inorganica Chimica Acta. 2018. Vol. 477. pp. 277-283.
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Kubasov A. S., Matveev E. Yu., Turyshev E. S., Polyakova I. V., Nichugovskiy A. I., Zhizhin K. Y., Kuznetsov N. T. Synthesis and stability studies of derivatives of the 2-sulfanyl-closo-decaborate anion [2-B10H9SH]2− // Inorganica Chimica Acta. 2018. Vol. 477. pp. 277-283.
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TY - JOUR
DO - 10.1016/j.ica.2018.03.013
UR - https://doi.org/10.1016%2Fj.ica.2018.03.013
TI - Synthesis and stability studies of derivatives of the 2-sulfanyl-closo-decaborate anion [2-B10H9SH]2−
T2 - Inorganica Chimica Acta
AU - Kubasov, Alexey S.
AU - Matveev, E Yu
AU - Turyshev, E S
AU - Polyakova, Irina V.
AU - Nichugovskiy, A I
AU - Zhizhin, Konstantin Yu.
AU - Kuznetsov, N. T.
PY - 2018
DA - 2018/05/01 00:00:00
PB - Elsevier
SP - 277-283
VL - 477
SN - 0020-1693
SN - 1873-3255
ER -
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@article{2018_Kubasov,
author = {Alexey S. Kubasov and E Yu Matveev and E S Turyshev and Irina V. Polyakova and A I Nichugovskiy and Konstantin Yu. Zhizhin and N. T. Kuznetsov},
title = {Synthesis and stability studies of derivatives of the 2-sulfanyl-closo-decaborate anion [2-B10H9SH]2−},
journal = {Inorganica Chimica Acta},
year = {2018},
volume = {477},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016%2Fj.ica.2018.03.013},
pages = {277--283},
doi = {10.1016/j.ica.2018.03.013}
}