Journal of Alloys and Compounds, volume 935, pages 168129

Au nanoparticles modified HNTs/g-C3N4/CdS composite for highly efficient CO2 photoreduction and tetracycline degradation

Wenhui Ma 1
Ye Zhu
Xuewu Wang
1
 
College of Science, Northeast Electric Power University, Changchun Road 169, 132012 Jilin, People’s Republic of China
Publication typeJournal Article
Publication date2023-02-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor6.2
ISSN09258388
Materials Chemistry
Metals and Alloys
Mechanical Engineering
Mechanics of Materials
Abstract
In this research, Au nanoparticles (NPs) modified HNTs/g-C 3 N 4 /CdS composite (HCAC-3) photocatalyst was prepared for highly-efficient photocatalytic reaction. SEM and TEM results confirmed that the g-C 3 N 4 was uniformly wrapped on the surface of HNTs, and Au and CdS NPs were also loaded on the surface of the HNTs/g-C 3 N 4 composite. Photo-electrochemistry tests and density functional theory calculation results showed that the introducing Au NPs speeds up the photo-electric conversion and separation ratio of photogenerated carriers inside the catalyst. Additionally, the CO 2 photoreduction experiments showed that the yields of CO and CH 4 with HCAC-3 catalyst after 4 h irradiation with UV-Vis light were about 55.4 and 8.6 μmol/g, respectively, which were about five times the performance of HNTs/g-C 3 N 4 composite and the HCAC-3 has great photocatalytic stability. Besides, the photodegradation experiment of tetracycline aqueous solution showed that the HCAC-3 composite has excellent photodegradation activity. After 120 min, the tetracycline photodegradation ratio of HCAC-3 was about 87.4%, which is about 2.2 times higher than that of HNTs/g-C 3 N 4 composite. Finally, the synergistic effect of g-C 3 N 4 /CdS type II heterojunction and the LSPR effect of Au NPs were investigated and determined as the main reasons for the improvement of the photocatalytic performance of the g-C 3 N 4 -based catalyst. • HNTs/g-C 3 N 4 /Au/CdS was prepared for CO 2 photoreduction and TC degradation • The dispersion of active sites was greatly enhanced by the loading of HNTs • Au NPs speed up the carriers’ separation efficiency in g-C 3 N 4 /CdS heterojunction

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Ma W., Zhu Y., Wang X. Au nanoparticles modified HNTs/g-C3N4/CdS composite for highly efficient CO2 photoreduction and tetracycline degradation // Journal of Alloys and Compounds. 2023. Vol. 935. p. 168129.
GOST all authors (up to 50) Copy
Ma W., Zhu Y., Wang X. Au nanoparticles modified HNTs/g-C3N4/CdS composite for highly efficient CO2 photoreduction and tetracycline degradation // Journal of Alloys and Compounds. 2023. Vol. 935. p. 168129.
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RIS Copy
TY - JOUR
DO - 10.1016/j.jallcom.2022.168129
UR - https://doi.org/10.1016/j.jallcom.2022.168129
TI - Au nanoparticles modified HNTs/g-C3N4/CdS composite for highly efficient CO2 photoreduction and tetracycline degradation
T2 - Journal of Alloys and Compounds
AU - Ma, Wenhui
AU - Zhu, Ye
AU - Wang, Xuewu
PY - 2023
DA - 2023/02/01 00:00:00
PB - Elsevier
SP - 168129
VL - 935
SN - 0925-8388
ER -
BibTex
Cite this
BibTex Copy
@article{2023_Ma,
author = {Wenhui Ma and Ye Zhu and Xuewu Wang},
title = {Au nanoparticles modified HNTs/g-C3N4/CdS composite for highly efficient CO2 photoreduction and tetracycline degradation},
journal = {Journal of Alloys and Compounds},
year = {2023},
volume = {935},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.jallcom.2022.168129},
pages = {168129},
doi = {10.1016/j.jallcom.2022.168129}
}
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