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Journal of Colloid and Interface Science, volume 540, pages 1-8

The superior photocatalytic activity of Nb doped TiO2/g-C3N4 direct Z-scheme system for efficient conversion of CO2 into valuable fuels

Nguyen Thi Thanh Truc
Nguyen Thi Ngoc TRUC 1
Bach Long Giang
Long Giang Bach 2
THI HANH NGUYEN 3
Thanh-Dong Pham
Thanh Dong Pham
Nguyen Thi Phuong Le Chi 4
Dinh Trinh Tran
Minh Viet Nguyen
Minh-Viet Nguyen
Van Noi Nguyen
Publication typeJournal Article
Publication date2019-03-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor9.9
ISSN00219797, 10957103
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Colloid and Surface Chemistry
Biomaterials
Abstract
In this study, we firstly aimed to use Nb as dopant to dope into the TiO2 lattice in order to narrow band gap energy or enhance photocatalytic activity of the Nb-TiO2. Then, the prepared Nb-TiO2 was combined with g-C3N4 to establish Nb-TiO2/g-C3N4 direct Z-scheme system for superior reduction of CO2 into valuable fuels even under visible light. The obtained results indicated that the band gap energy of the Nb-TiO2 (2.91 eV) was lower than that of the TiO2 (3.2 eV). In the successfully established Nb-TiO2/g-C3N4 direct Z-scheme system, the photo-excited e- in the CB of the Nb-TiO2 combined with the photo-excited h+ in the VB of the g-C3N4 preserving the existence of e- in the CB of the g-C3N4 and h+ in the VB of Nb-TiO2, and thereby, the system produced numerous amount of available e-/h+ pairs for the reduction of CO2 into various valuable fuels. In addition, the produced e- of the Nb-TiO2/g-C3N4 existing in the CB of the g-C3N4, which the potential energy is approximately -1.2 V, would be strong enough for the reduction of CO2 to generate not only CH4 and CO but also HCOOH. Among established Nb-TiO2/g-C3N4 materials, the 50Nb-TiO2/50 g-C3N4 material was the best material for the CO2 reduction.

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GOST Copy
Thanh Truc N. T. et al. The superior photocatalytic activity of Nb doped TiO2/g-C3N4 direct Z-scheme system for efficient conversion of CO2 into valuable fuels // Journal of Colloid and Interface Science. 2019. Vol. 540. pp. 1-8.
GOST all authors (up to 50) Copy
Thanh Truc N. T., TRUC N. T. N., Giang B. L., Bach L. G., NGUYEN T. H., Pham T., Pham T. D., Thi Phuong Le Chi N., Tran D. T., Nguyen M. V., Nguyen M., Nguyen V. N. The superior photocatalytic activity of Nb doped TiO2/g-C3N4 direct Z-scheme system for efficient conversion of CO2 into valuable fuels // Journal of Colloid and Interface Science. 2019. Vol. 540. pp. 1-8.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.jcis.2019.01.005
UR - https://doi.org/10.1016/j.jcis.2019.01.005
TI - The superior photocatalytic activity of Nb doped TiO2/g-C3N4 direct Z-scheme system for efficient conversion of CO2 into valuable fuels
T2 - Journal of Colloid and Interface Science
AU - Thanh Truc, Nguyen Thi
AU - Giang, Bach Long
AU - NGUYEN, THI HANH
AU - Pham, Thanh-Dong
AU - Thi Phuong Le Chi, Nguyen
AU - Tran, Dinh Trinh
AU - Nguyen, Minh Viet
AU - Nguyen, Van Noi
AU - TRUC, Nguyen Thi Ngoc
AU - Bach, Long Giang
AU - Pham, Thanh Dong
AU - Nguyen, Minh-Viet
PY - 2019
DA - 2019/03/01 00:00:00
PB - Elsevier
SP - 1-8
VL - 540
SN - 0021-9797
SN - 1095-7103
ER -
BibTex
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BibTex Copy
@article{2019_Thanh Truc,
author = {Nguyen Thi Thanh Truc and Bach Long Giang and THI HANH NGUYEN and Thanh-Dong Pham and Nguyen Thi Phuong Le Chi and Dinh Trinh Tran and Minh Viet Nguyen and Van Noi Nguyen and Nguyen Thi Ngoc TRUC and Long Giang Bach and Thanh Dong Pham and Minh-Viet Nguyen},
title = {The superior photocatalytic activity of Nb doped TiO2/g-C3N4 direct Z-scheme system for efficient conversion of CO2 into valuable fuels},
journal = {Journal of Colloid and Interface Science},
year = {2019},
volume = {540},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.jcis.2019.01.005},
pages = {1--8},
doi = {10.1016/j.jcis.2019.01.005}
}
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