Journal of Environmental Chemical Engineering, volume 12, issue 3, pages 112763
Base-free synthesis of renewable furan-2,5-dicarboxylic acid (FDCA) over an earth-abundant magnetic catalyst
SURABHI PANDEY
1
,
Marie Mottoul
2
,
Valérie Orsat
,
Valerie Orsat
1
,
Jean-François Morin
,
Jean-Francois Morin
3
,
Marie-Josée Dumont
2
2
Department of Chemical Engineering, Université Laval, Pavillon Adrien-Pouliot, 1065 avenue de la Médecine, QC G1V 0A6, Canada
|
3
Department of Chemistry, Université Laval, Pavillon Alexandre Vachon, 1045 avenue de la Médecine, QC G1V 0A6, Canada
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Publication type: Journal Article
Publication date: 2024-06-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 7.7
ISSN: 22133437
Process Chemistry and Technology
Pollution
Waste Management and Disposal
Chemical Engineering (miscellaneous)
Abstract
Being a biobased alternative to petroleum-based terephthalic acid (TPA), furan-2,5-dicarboxylic acid (FDCA) requires a low-cost and efficient catalytic system for its commercialization. This study describes FDCA production using whey permeate powder (WPP)-derived 5-(hydroxymethyl)furfural (HMF) in a base-free system over a magnetically recyclable catalyst composed of earth-abundant metals (Mn and Fe). The impact of MnCl2·4 H2O loading on the iron core was studied at different levels and found optimal at the ratio of 1:1. The in-situ oxidation of HMF was carried out using ozone and t-BuOOH as the oxidants in a γ-valerolactone (GVL) -water solvent system. It was observed that the ozone pre-treatment (3 h at room temperature) of HMF increased the FDCA yield from 39.7 % (without ozonation) to 60 % at a reaction condition of 130 °C for 2 h. The concentration profiles for the intermediates formed during HMF to FDCA oxidation i.e., 5-hydroxymethyl-2-furancarboxylic acid (HMFCA), furan-2,5-dicarbaldehyde (DFF), and 5-formyl-2-furancarboxylic acid (FFCA) were analyzed at different reaction temperatures to evaluate the reaction kinetics. The kinetic study revealed that the present solvent-catalytic system favored HMFCA formation over DFF due to the requirement of higher activation energy for the latter. The HMF to FDCA catalytic solvent was tested for WPP, which afforded an overall FDCA yield of 14.6 % at 130 °C in 120 min. In addition, the Mn1Fe1 consisted of mixed phases of Mn3O4, Mn2O3, MnO2, Fe2O3, and Fe3O4 and demonstrated variation in oxidation states for Mn (Mn3+↔Mn2+) and Fe (Fe2+↔Fe3+) species.
Top-30
Citations by journals
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Materials Today Communications
1 publication, 100%
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Citations by publishers
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Elsevier
1 publication, 100%
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PANDEY S. et al. Base-free synthesis of renewable furan-2,5-dicarboxylic acid (FDCA) over an earth-abundant magnetic catalyst // Journal of Environmental Chemical Engineering. 2024. Vol. 12. No. 3. p. 112763.
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PANDEY S., Mottoul M., Orsat V., Orsat V., Morin J., Morin J., Dumont M. Base-free synthesis of renewable furan-2,5-dicarboxylic acid (FDCA) over an earth-abundant magnetic catalyst // Journal of Environmental Chemical Engineering. 2024. Vol. 12. No. 3. p. 112763.
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TY - JOUR
DO - 10.1016/j.jece.2024.112763
UR - https://doi.org/10.1016/j.jece.2024.112763
TI - Base-free synthesis of renewable furan-2,5-dicarboxylic acid (FDCA) over an earth-abundant magnetic catalyst
T2 - Journal of Environmental Chemical Engineering
AU - PANDEY, SURABHI
AU - Mottoul, Marie
AU - Orsat, Valerie
AU - Morin, Jean-Francois
AU - Dumont, Marie-Josée
AU - Orsat, Valérie
AU - Morin, Jean-François
PY - 2024
DA - 2024/06/01 00:00:00
PB - Elsevier
SP - 112763
IS - 3
VL - 12
SN - 2213-3437
ER -
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@article{2024_PANDEY,
author = {SURABHI PANDEY and Marie Mottoul and Valerie Orsat and Jean-Francois Morin and Marie-Josée Dumont and Valérie Orsat and Jean-François Morin},
title = {Base-free synthesis of renewable furan-2,5-dicarboxylic acid (FDCA) over an earth-abundant magnetic catalyst},
journal = {Journal of Environmental Chemical Engineering},
year = {2024},
volume = {12},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.jece.2024.112763},
number = {3},
pages = {112763},
doi = {10.1016/j.jece.2024.112763}
}
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PANDEY, SURABHI, et al. “Base-free synthesis of renewable furan-2,5-dicarboxylic acid (FDCA) over an earth-abundant magnetic catalyst.” Journal of Environmental Chemical Engineering, vol. 12, no. 3, Jun. 2024, p. 112763. https://doi.org/10.1016/j.jece.2024.112763.