Journal of Luminescence, volume 247, pages 118877
Spectral and infrared luminescent characteristics of 40PbO–35Bi2O3–25Ga2O3 glasses doped with Er3+
Publication type: Journal Article
Publication date: 2022-07-01
Journal:
Journal of Luminescence
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 3.6
ISSN: 00222313
General Chemistry
Biochemistry
Biophysics
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Abstract
The heavy metal oxide glasses based on 40PbO–35Bi 2 O 3 –25Ga 2 O 3 composition doped with different Er 3+ ions content were synthesized in corundum crucible. The concentration dependences of band gap energy and Urbach energy in a series of glass samples were analyzed. The studied matrix showed wider IR transparency region comparing with other heavy metal oxide glasses containing PbO: up to 6.5 μm. The content of hydroxyl impurities N OH was evaluated based on infrared transmission spectra. The comparison of obtained N OH values with other oxide glasses indicate that studied composition has a moderate hydroxyl groups content. Luminescence properties of 4 I 13/2 → 4 I 15/2 transition were measured under 980 nm wavelength excitation. The correlation of radiative characteristics with N OH content was determined. The maximum relative luminescence intensity had the sample doped with 0.869 × 10 20 ion/cm 3 of Er 3+ . Comparative analysis of FWHM, peak value of emission cross-section, and radiative lifetime of 4 I 13/2 → 4 I 15/2 transition with other glass matrixes indicates the prospects of the investigated composition as advanced material for 1.5 μm optical amplifiers. • The 40PbO–35Bi 2 O 3 –25Ga 2 O 3 glasses were synthesized in corundum crucible. • LBG matrix has better spectroscopic properties than other [BiO–PbO-GaO] glasses. • The correlation between the IR radiative characteristics and N OH was found. • The calculated σ em peak value of 4 I 13/2 . → 4 I 15/2 transition was 9.0 × 10 −21 cm 2 • Tauc's plot and Urbach's energy were obtained for a glasses with different Er 3+ content.
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Klinkov V. A. et al. Spectral and infrared luminescent characteristics of 40PbO–35Bi2O3–25Ga2O3 glasses doped with Er3+ // Journal of Luminescence. 2022. Vol. 247. p. 118877.
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Klinkov V. A., Tsimerman E., Semencha A. V., Babkina A. Spectral and infrared luminescent characteristics of 40PbO–35Bi2O3–25Ga2O3 glasses doped with Er3+ // Journal of Luminescence. 2022. Vol. 247. p. 118877.
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TY - JOUR
DO - 10.1016/j.jlumin.2022.118877
UR - https://doi.org/10.1016%2Fj.jlumin.2022.118877
TI - Spectral and infrared luminescent characteristics of 40PbO–35Bi2O3–25Ga2O3 glasses doped with Er3+
T2 - Journal of Luminescence
AU - Klinkov, Victor A
AU - Tsimerman, Evgenia
AU - Semencha, A V
AU - Babkina, A
PY - 2022
DA - 2022/07/01 00:00:00
PB - Elsevier
SP - 118877
VL - 247
SN - 0022-2313
ER -
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@article{2022_Klinkov,
author = {Victor A Klinkov and Evgenia Tsimerman and A V Semencha and A Babkina},
title = {Spectral and infrared luminescent characteristics of 40PbO–35Bi2O3–25Ga2O3 glasses doped with Er3+},
journal = {Journal of Luminescence},
year = {2022},
volume = {247},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016%2Fj.jlumin.2022.118877},
pages = {118877},
doi = {10.1016/j.jlumin.2022.118877}
}