Latent metathesis catalyst stabilized with NO2⋯I interaction
Publication type: Journal Article
Publication date: 2013-11-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A modified Hoveyda–Grubbs metathesis catalyst incorporating a chelating 2-iodo-3-nitrobenzylidene ligand is described. The complex displays very little activity in model metathesis reactions at rt, while easily initiates at slightly elevated temperatures. Latent behavior of the catalyst is attributed to a through-space electron-donating effect of the nitro group, which stabilizes the chelate by the formation of NO2 → I → Ru triad.
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13
Total citations:
13
Citations from 2024:
1
(7.69%)
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Barbasiewicz M., Malinska M., Błocki K. Latent metathesis catalyst stabilized with NO2⋯I interaction // Journal of Organometallic Chemistry. 2013. Vol. 745-746. pp. 8-11.
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Barbasiewicz M., Malinska M., Błocki K. Latent metathesis catalyst stabilized with NO2⋯I interaction // Journal of Organometallic Chemistry. 2013. Vol. 745-746. pp. 8-11.
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TY - JOUR
DO - 10.1016/j.jorganchem.2013.06.030
UR - https://doi.org/10.1016/j.jorganchem.2013.06.030
TI - Latent metathesis catalyst stabilized with NO2⋯I interaction
T2 - Journal of Organometallic Chemistry
AU - Barbasiewicz, Michał
AU - Malinska, Maura
AU - Błocki, Krzysztof
PY - 2013
DA - 2013/11/01
PB - Elsevier
SP - 8-11
VL - 745-746
SN - 0022-328X
SN - 1872-8561
ER -
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BibTex (up to 50 authors)
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@article{2013_Barbasiewicz,
author = {Michał Barbasiewicz and Maura Malinska and Krzysztof Błocki},
title = {Latent metathesis catalyst stabilized with NO2⋯I interaction},
journal = {Journal of Organometallic Chemistry},
year = {2013},
volume = {745-746},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/j.jorganchem.2013.06.030},
pages = {8--11},
doi = {10.1016/j.jorganchem.2013.06.030}
}