Contribution of ammonium ions to sulfidation-flotation of smithsonite

Dandan Wu
Wenhui Ma
Shuming Wen
Shaojun Bai
Jiushuai Deng
Qiong Yin
Publication typeJournal Article
Publication date2017-09-01
scimago Q1
wos Q1
SJR0.982
CiteScore10.8
Impact factor6.3
ISSN18761070, 18761089
General Chemistry
General Chemical Engineering
Abstract
Sulfidation-flotation is commonly performed to recover base metal oxide ores. Sulfidation could become the key process in recovering zinc from zinc oxide ores. We investigated the common zinc oxide mineral. An ammonium salt was used to enhance sulfidation-flotation of smithsonite. The effect of ammonium ions on sulfidation and flotation of smithsonite was investigated by microflotation, inductively coupled plasma analysis, scanning electron microscopy, and X-ray photoelectron spectroscopy. Addition of the ammonium salt facilitates flotation of smithsonite and improves the flotation recovery by ∼25%. Solubility tests under different conditions indicate that the surface solubility of smithsonite in the presence of ammonium ions significantly decreases. Energy-dispersive X-ray spectroscopy based semi-quantitative analysis shows that the concentration of sulfur on the ammonium enhanced sulfurized smithsonite surface is 8.55%, whereas that on the sulfurized smithsonite surface is 2%. XPS analysis reveals that smithsonite is more easily sulfurized by sodium sulfide in the presence of ammonium ions. Therefore, ammonium ion addition can be used to enhance sulfidation of smithsonite and improve the flotation performance.
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GOST Copy
Wu D. et al. Contribution of ammonium ions to sulfidation-flotation of smithsonite // Journal of the Taiwan Institute of Chemical Engineers. 2017. Vol. 78. pp. 20-26.
GOST all authors (up to 50) Copy
Wu D., Ma W., Wen S., Bai S., Deng J., Yin Q. Contribution of ammonium ions to sulfidation-flotation of smithsonite // Journal of the Taiwan Institute of Chemical Engineers. 2017. Vol. 78. pp. 20-26.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.jtice.2017.05.015
UR - https://doi.org/10.1016/j.jtice.2017.05.015
TI - Contribution of ammonium ions to sulfidation-flotation of smithsonite
T2 - Journal of the Taiwan Institute of Chemical Engineers
AU - Wu, Dandan
AU - Ma, Wenhui
AU - Wen, Shuming
AU - Bai, Shaojun
AU - Deng, Jiushuai
AU - Yin, Qiong
PY - 2017
DA - 2017/09/01
PB - Taiwan Institute of Chemical Engineers
SP - 20-26
VL - 78
SN - 1876-1070
SN - 1876-1089
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2017_Wu,
author = {Dandan Wu and Wenhui Ma and Shuming Wen and Shaojun Bai and Jiushuai Deng and Qiong Yin},
title = {Contribution of ammonium ions to sulfidation-flotation of smithsonite},
journal = {Journal of the Taiwan Institute of Chemical Engineers},
year = {2017},
volume = {78},
publisher = {Taiwan Institute of Chemical Engineers},
month = {sep},
url = {https://doi.org/10.1016/j.jtice.2017.05.015},
pages = {20--26},
doi = {10.1016/j.jtice.2017.05.015}
}