Open Access
Open access
volume 126 pages 29-36

Designing bio-based plasticizers: Effect of alkyl chain length on plasticization properties of isosorbide diesters in PVC blends

Publication typeJournal Article
Publication date2017-07-01
scimago Q1
wos Q1
SJR1.727
CiteScore14.9
Impact factor7.9
ISSN02641275, 18734197
General Materials Science
Mechanical Engineering
Mechanics of Materials
Abstract
A series of bio-based plasticizers based on isosorbide, a renewable monomer derived from glucose, were successfully synthesized. The chemical structures of the synthesized isosorbide diesters with different alkyl chain length were confirmed by FTIR and 1H NMR. The influence of varying alkyl chain length on thermal and mechanical properties of isosorbide diesters in poly(vinyl chloride) (PVC) was investigated in detail. It was found that the plasticizing efficiency of isosorbide diester decreased as the alkyl chain length increased, reflecting on the gradually increased Tg and the decreased elongation at break of PVC blend. However, the longer alkyl chain length of isosorbide diester improved the thermal stability of PVC blend and simultaneously depressed its volatility from PVC. Besides, the bio-based isosorbide diesters rivaled those petro-based phthalates, and they could be potential candidates to replace phthalates in the future industry.
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GOST |
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GOST Copy
Yang Y. et al. Designing bio-based plasticizers: Effect of alkyl chain length on plasticization properties of isosorbide diesters in PVC blends // Materials and Design. 2017. Vol. 126. pp. 29-36.
GOST all authors (up to 50) Copy
Yang Y., Huang J., Zhang R., Zhu J. Designing bio-based plasticizers: Effect of alkyl chain length on plasticization properties of isosorbide diesters in PVC blends // Materials and Design. 2017. Vol. 126. pp. 29-36.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.matdes.2017.04.005
UR - https://doi.org/10.1016/j.matdes.2017.04.005
TI - Designing bio-based plasticizers: Effect of alkyl chain length on plasticization properties of isosorbide diesters in PVC blends
T2 - Materials and Design
AU - Yang, Yong
AU - Huang, Juncheng
AU - Zhang, Ruoyu
AU - Zhu, Jin
PY - 2017
DA - 2017/07/01
PB - Elsevier
SP - 29-36
VL - 126
SN - 0264-1275
SN - 1873-4197
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2017_Yang,
author = {Yong Yang and Juncheng Huang and Ruoyu Zhang and Jin Zhu},
title = {Designing bio-based plasticizers: Effect of alkyl chain length on plasticization properties of isosorbide diesters in PVC blends},
journal = {Materials and Design},
year = {2017},
volume = {126},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.matdes.2017.04.005},
pages = {29--36},
doi = {10.1016/j.matdes.2017.04.005}
}