Co-precipitation of yttrium and barium fluorides from aqueous solutions
Maria N Mayakova
1
,
Sergey Kuznetsov
1
,
V. Voronov
1
,
Roman P Ermakov
1
,
Kseniya S Samarina
1
,
Arthur I. Popov
1
,
Vyacheslav V Osiko
1
Publication type: Journal Article
Publication date: 2012-07-01
scimago Q1
wos Q2
SJR: 0.943
CiteScore: 9.9
Impact factor: 5.7
ISSN: 00255408, 18734227
Condensed Matter Physics
General Materials Science
Mechanical Engineering
Mechanics of Materials
Abstract
Co-precipitation of barium and yttrium fluorides from aqueous solutions at room temperature produced non-equilibrium Ba1−xYxF2+x nanofluoride phase with face-centered cubic crystal lattice of fluorite-type with the composition interval of the homogeneity for x = 0.35–0.75. Lattice parameter a of this solid solution nanophase varied as a function of the sample chemical composition in a complex manner with two areas of linear dependency, from x = 0.35 to 0.45 and from x = 0.50 to 0.75. A plausible explanation of this phenomenon included a change of the type of crystal lattice defects and the manner of their population with the corresponding ions. An increase of the relative amount of yttrium in the HF reaction system led to the formation of hydroxonium salt of decafluorotriyttrium acid, (H3O+)Y3F10−·nH2O, instead of expected YF3 hydrate. No formation of oxyfluoride phases under acidic conditions has been observed.
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GOST
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P. P. Fedorov P. P. F. et al. Co-precipitation of yttrium and barium fluorides from aqueous solutions // Materials Research Bulletin. 2012. Vol. 47. No. 7. pp. 1794-1799.
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P. P. Fedorov P. P. F., Mayakova M. N., Kuznetsov S., Voronov V., Ermakov R. P., Samarina K. S., Popov A. I., Osiko V. V. Co-precipitation of yttrium and barium fluorides from aqueous solutions // Materials Research Bulletin. 2012. Vol. 47. No. 7. pp. 1794-1799.
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RIS
Copy
TY - JOUR
DO - 10.1016/j.materresbull.2012.03.027
UR - https://doi.org/10.1016/j.materresbull.2012.03.027
TI - Co-precipitation of yttrium and barium fluorides from aqueous solutions
T2 - Materials Research Bulletin
AU - P. P. Fedorov, P. P. Fedorov
AU - Mayakova, Maria N
AU - Kuznetsov, Sergey
AU - Voronov, V.
AU - Ermakov, Roman P
AU - Samarina, Kseniya S
AU - Popov, Arthur I.
AU - Osiko, Vyacheslav V
PY - 2012
DA - 2012/07/01
PB - Elsevier
SP - 1794-1799
IS - 7
VL - 47
SN - 0025-5408
SN - 1873-4227
ER -
Cite this
BibTex (up to 50 authors)
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@article{2012_P. P. Fedorov,
author = {P. P. Fedorov P. P. Fedorov and Maria N Mayakova and Sergey Kuznetsov and V. Voronov and Roman P Ermakov and Kseniya S Samarina and Arthur I. Popov and Vyacheslav V Osiko},
title = {Co-precipitation of yttrium and barium fluorides from aqueous solutions},
journal = {Materials Research Bulletin},
year = {2012},
volume = {47},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.materresbull.2012.03.027},
number = {7},
pages = {1794--1799},
doi = {10.1016/j.materresbull.2012.03.027}
}
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MLA
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P. P. Fedorov, P. P. Fedorov, et al. “Co-precipitation of yttrium and barium fluorides from aqueous solutions.” Materials Research Bulletin, vol. 47, no. 7, Jul. 2012, pp. 1794-1799. https://doi.org/10.1016/j.materresbull.2012.03.027.