Journal of Membrane Science, volume 612, pages 118408

Development of surface-sulfonated graft anion-exchange membranes with monovalent ion selectivity and antifouling properties for electromembrane processes

Golubenko Daniil ^{1, 2}

Yaroslavtsev A. B. ^{1, 2}

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Kurnakov Institute of General and Inorganic Chemistry of Russian Academy of Sciences, 31 Leninsky Avenue, 119991, Moscow, Russian Federation |

National Research University Higher School of Economics, 20 Myasnitskaya Street, 101000, Moscow, Russian Federation |

Publication type: Journal Article

Publication date: 2020-10-01

Elsevier

Journal: Journal of Membrane Science

Quartile SCImago

Quartile WOS

Impact factor: 9.5

ISSN: 03767388

DOI: 10.1016/j.memsci.2020.118408

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Biochemistry

Physical and Theoretical Chemistry

General Materials Science

Filtration and Separation

Abstract

This communication describes the development of anion-exchange membrane (AEM) with a modified surface possessing monovalent ion selectivity and antifouling properties. Modified AEMs series was obtained by the formation of an oppositely-charged thin layer utilizing the surface sulfonation of the grafted AEMs. The creation of the interface layer leads to a significant increase in the Cl/SO4 selectivity and the appearance of humic acid sorption resistance. The best surface-sulfonated anion-exchange membrane (s-AEM) has a high ionic conductivity of 11.2 mS cm−1 and high Cl/SO4 selectivity up to 6.4 in electrodialysis. The sulfonated layer was characterized by IR spectroscopy and electron microscopy. The relationship between the structure and thickness of the cation-exchange surface layer and the observed changes in membrane transport properties such as diffusion permeability, ionic conductivity, potentiometric transport numbers, and current-voltage characteristics are discussed. It was shown that the Cl/SO4 selectivity of s-AEM in the desalination process depends on the current density. The obtained data were successfully interpreted using a mathematical model based on the concept of the bipolar structure of the s-AEM surface layer and diffusion control of anion transport through it.

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Citations by journals

	1 2 3 4
Membranes	Membranes, 4, 12.9% Membranes 4 publications, 12.9%
Journal of Membrane Science	Journal of Membrane Science, 4, 12.9% Journal of Membrane Science 4 publications, 12.9%
Separation and Purification Technology	Separation and Purification Technology, 3, 9.68% Separation and Purification Technology 3 publications, 9.68%
International Journal of Molecular Sciences	International Journal of Molecular Sciences, 2, 6.45% International Journal of Molecular Sciences 2 publications, 6.45%
Membranes and Membrane Technologies	Membranes and Membrane Technologies, 2, 6.45% Membranes and Membrane Technologies 2 publications, 6.45%
Chemical Engineering Science	Chemical Engineering Science, 2, 6.45% Chemical Engineering Science 2 publications, 6.45%
Colloid Journal	Colloid Journal, 2, 6.45% Colloid Journal 2 publications, 6.45%
International Dairy Journal	International Dairy Journal, 1, 3.23% International Dairy Journal 1 publication, 3.23%
Polymers	Polymers, 1, 3.23% Polymers 1 publication, 3.23%
Surfaces and Interfaces	Surfaces and Interfaces, 1, 3.23% Surfaces and Interfaces 1 publication, 3.23%
International Journal of Environmental Science and Technology	International Journal of Environmental Science and Technology, 1, 3.23% International Journal of Environmental Science and Technology 1 publication, 3.23%
ACS Applied Polymer Materials	ACS Applied Polymer Materials, 1, 3.23% ACS Applied Polymer Materials 1 publication, 3.23%
ACS Applied Energy Materials	ACS Applied Energy Materials, 1, 3.23% ACS Applied Energy Materials 1 publication, 3.23%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 1, 3.23% Journal of Materials Chemistry A 1 publication, 3.23%
Solvent Extraction and Ion Exchange	Solvent Extraction and Ion Exchange, 1, 3.23% Solvent Extraction and Ion Exchange 1 publication, 3.23%
Desalination	Desalination, 1, 3.23% Desalination 1 publication, 3.23%
Materials Today Chemistry	Materials Today Chemistry, 1, 3.23% Materials Today Chemistry 1 publication, 3.23%
	1 2 3 4

Citations by publishers

	2 4 6 8 10 12 14
Elsevier	Elsevier, 13, 41.94% Elsevier 13 publications, 41.94%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 7, 22.58% Multidisciplinary Digital Publishing Institute (MDPI) 7 publications, 22.58%
Pleiades Publishing	Pleiades Publishing, 4, 12.9% Pleiades Publishing 4 publications, 12.9%
American Chemical Society (ACS)	American Chemical Society (ACS), 2, 6.45% American Chemical Society (ACS) 2 publications, 6.45%
Springer Nature	Springer Nature, 1, 3.23% Springer Nature 1 publication, 3.23%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 3.23% Royal Society of Chemistry (RSC) 1 publication, 3.23%
Taylor & Francis	Taylor & Francis, 1, 3.23% Taylor & Francis 1 publication, 3.23%
	2 4 6 8 10 12 14

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Golubenko D. et al. Development of surface-sulfonated graft anion-exchange membranes with monovalent ion selectivity and antifouling properties for electromembrane processes // Journal of Membrane Science. 2020. Vol. 612. p. 118408.

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Golubenko D., Yaroslavtsev A. B. Development of surface-sulfonated graft anion-exchange membranes with monovalent ion selectivity and antifouling properties for electromembrane processes // Journal of Membrane Science. 2020. Vol. 612. p. 118408.

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RIS Copy

TY - JOUR

DO - 10.1016/j.memsci.2020.118408

UR - https://doi.org/10.1016%2Fj.memsci.2020.118408

TI - Development of surface-sulfonated graft anion-exchange membranes with monovalent ion selectivity and antifouling properties for electromembrane processes

T2 - Journal of Membrane Science

AU - Golubenko, Daniil

AU - Yaroslavtsev, A. B.

PY - 2020

DA - 2020/10/01 00:00:00

PB - Elsevier

SP - 118408

VL - 612

SN - 0376-7388

ER -

BibTex

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BibTex Copy

@article{2020_Golubenko,

author = {Daniil Golubenko and A. B. Yaroslavtsev},

title = {Development of surface-sulfonated graft anion-exchange membranes with monovalent ion selectivity and antifouling properties for electromembrane processes},

journal = {Journal of Membrane Science},

year = {2020},

volume = {612},

publisher = {Elsevier},

month = {oct},

url = {https://doi.org/10.1016%2Fj.memsci.2020.118408},

pages = {118408},

doi = {10.1016/j.memsci.2020.118408}

}

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Publisher

Elsevier

Journal

Journal of Membrane Science

Quartile SCImago

Quartile WOS

Impact factor

9.5

ISSN

03767388 (Print)

Labs

Laboratory of Ionics of Functional Materials

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