Mendeleev Communications

, volume 31 , issue 5 , pages 686-689

Stereoselective approach to conjugated enone oximes from aliphatic nitro compounds and sulfur ylides

Rauf T Akhmirov ^{1, 2}

Sema L. Ioffe ³

Alexey Yu Sukhorukov ³

Hide authors affiliations Show authors affiliations: 3 affiliations

D. I. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russian Federation |

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation |

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991,Moscow, Russian Federation |

Publication type: Journal Article

Publication date: 2021-09-01

OOO Zhurnal "Mendeleevskie Soobshcheniya"

Mendeleev Communications

scimago Q3

wos Q3

SJR: 0.305

CiteScore: 3.0

Impact factor: 1.7

ISSN: 09599436, 1364551X

DOI: 10.1016/j.mencom.2021.09.031

Copy DOI

General Chemistry

Abstract

A novel approach to conjugated enone oximes from aliphatic nitro compounds deals with double silylation of N,N -bis(silyloxy) enamines followed by a stereoselective reaction with an ester-stabilized sulfur ylide. The proposed mechanism involves the generation of labile nitrosoalkenes as intermediates, which react with the sulfur ylide to give target enone oximes.

Found

1 citation

Sukhorukov Alexey

DSc in Chemistry

123 publications, 1 630 citations, 97 reviews

h-index: 22

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Research interests

Medicinal Chemistry

Organic Chemistry

Top-30

Journals

	1
Organic Chemistry Frontiers	Organic Chemistry Frontiers, 1, 50% Organic Chemistry Frontiers 1 publication, 50%
Organic Reaction Mechanisms	Organic Reaction Mechanisms, 1, 50% Organic Reaction Mechanisms 1 publication, 50%
	1

Publishers

	1
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 50% Royal Society of Chemistry (RSC) 1 publication, 50%
Wiley	Wiley, 1, 50% Wiley 1 publication, 50%
	1

We do not take into account publications without a DOI.
Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Akhmirov R. T. et al. Stereoselective approach to conjugated enone oximes from aliphatic nitro compounds and sulfur ylides // Mendeleev Communications. 2021. Vol. 31. No. 5. pp. 686-689.

GOST all authors (up to 50) Copy

Akhmirov R. T., Ioffe S. L., Sukhorukov A. Yu. Stereoselective approach to conjugated enone oximes from aliphatic nitro compounds and sulfur ylides // Mendeleev Communications. 2021. Vol. 31. No. 5. pp. 686-689.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.mencom.2021.09.031

UR - https://doi.org/10.1016/j.mencom.2021.09.031

TI - Stereoselective approach to conjugated enone oximes from aliphatic nitro compounds and sulfur ylides

T2 - Mendeleev Communications

AU - Akhmirov, Rauf T

AU - Ioffe, Sema L.

AU - Sukhorukov, Alexey Yu

PY - 2021

DA - 2021/09/01

PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"

SP - 686-689

IS - 5

VL - 31

SN - 0959-9436

SN - 1364-551X

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2021_Akhmirov,

author = {Rauf T Akhmirov and Sema L. Ioffe and Alexey Yu Sukhorukov},

title = {Stereoselective approach to conjugated enone oximes from aliphatic nitro compounds and sulfur ylides},

journal = {Mendeleev Communications},

year = {2021},

volume = {31},

publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},

month = {sep},

url = {https://doi.org/10.1016/j.mencom.2021.09.031},

number = {5},

pages = {686--689},

doi = {10.1016/j.mencom.2021.09.031}

}

MLA

Cite this

MLA Copy

Akhmirov, Rauf T., et al. “Stereoselective approach to conjugated enone oximes from aliphatic nitro compounds and sulfur ylides.” Mendeleev Communications, vol. 31, no. 5, Sep. 2021, pp. 686-689. https://doi.org/10.1016/j.mencom.2021.09.031.