volume 33 issue 1 pages 24-26

Diversifying the superbase-catalyzed C=N bond ethynylation: triaryl-1-pyrrolines and triaryl-1H-pyrroles from N-benzyl aldimines and arylacetylenes

Publication typeJournal Article
Publication date2023-01-01
scimago Q3
wos Q3
SJR0.305
CiteScore3.0
Impact factor1.7
ISSN09599436, 1364551X
General Chemistry
Abstract
N-Benzyl aldimines react with arylacetylenes in the presence of ButOK/DMSO superbase system to afford 2,3,5-triaryl-1-pyrrolines as two tautomers with 1,2- and 1,5-location of the double bond, both being the trans-diastereomers. This version of the C=N bond ethynylation differs from the previous one with N-benzyl ketimines. The oxidation of the pyrroline tautomeric mixtures without their isolation gives 2,3,5-triaryl-1H-pyrroles.
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Bidusenko I. A. et al. Diversifying the superbase-catalyzed C=N bond ethynylation: triaryl-1-pyrrolines and triaryl-1H-pyrroles from N-benzyl aldimines and arylacetylenes // Mendeleev Communications. 2023. Vol. 33. No. 1. pp. 24-26.
GOST all authors (up to 50) Copy
Bidusenko I. A., Schmidt E. Yu., Protsuk N. I., Ushakov I. A., Trofimov B. A. Diversifying the superbase-catalyzed C=N bond ethynylation: triaryl-1-pyrrolines and triaryl-1H-pyrroles from N-benzyl aldimines and arylacetylenes // Mendeleev Communications. 2023. Vol. 33. No. 1. pp. 24-26.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2023.01.007
UR - https://doi.org/10.1016/j.mencom.2023.01.007
TI - Diversifying the superbase-catalyzed C=N bond ethynylation: triaryl-1-pyrrolines and triaryl-1H-pyrroles from N-benzyl aldimines and arylacetylenes
T2 - Mendeleev Communications
AU - Bidusenko, Ivan A
AU - Schmidt, Elena Yu
AU - Protsuk, Nadezhda I
AU - Ushakov, I A
AU - Trofimov, B. A.
PY - 2023
DA - 2023/01/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 24-26
IS - 1
VL - 33
SN - 0959-9436
SN - 1364-551X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2023_Bidusenko,
author = {Ivan A Bidusenko and Elena Yu Schmidt and Nadezhda I Protsuk and I A Ushakov and B. A. Trofimov},
title = {Diversifying the superbase-catalyzed C=N bond ethynylation: triaryl-1-pyrrolines and triaryl-1H-pyrroles from N-benzyl aldimines and arylacetylenes},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jan},
url = {https://doi.org/10.1016/j.mencom.2023.01.007},
number = {1},
pages = {24--26},
doi = {10.1016/j.mencom.2023.01.007}
}
MLA
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MLA Copy
Bidusenko, Ivan A., et al. “Diversifying the superbase-catalyzed C=N bond ethynylation: triaryl-1-pyrrolines and triaryl-1H-pyrroles from N-benzyl aldimines and arylacetylenes.” Mendeleev Communications, vol. 33, no. 1, Jan. 2023, pp. 24-26. https://doi.org/10.1016/j.mencom.2023.01.007.
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