The growth of mixed alkaline-earth fluorides for laser host applications

A comprehensive analysis is implemented concerning the growth, properties, and applications of doped–co-doped single and mixed alkali earth fluoride systems. Calcium–strontium fluoride solid solutions with a Sr content proportion varying widely between 0.007 and 0.675 mol.% are obtained as a batch of axis-symmetrical boules grown by a Bridgman–Stockbarger (BS) method. The crystallization front (CF) can be controlled to retain a convex CF-shape that is favourable for normal growth of single crystals . This achieved using a broad adiabatic furnace zone (AdZ) independently of the boules’ composition. The influence of the thermal field distribution on the CF and the real crystallization rate (CR), which are both critically decisive in controlling crystal quality, were originally assessed using empirically derived formulas. The optical characteristics of the grown boules were monitored by measuring the external transmittance t and calculating the total losses following light irradiation of optical windows that were prepared from sections of the boules that had been cut parallel to one another. The t -measurements were performed by two different techniques and the comparative analysis of the results reliably indicates any inhomogeneity in the grown boules. A simple supercooling criterion proved to closely relate the morphological stability of the CF enabling one to set up the optimum growth conditions. Thus the normal growth criterion outlines the concentration bounds where the isotropic growth mechanism is replaced by cellular anisotropic growth. A procedure has been established for provisioning researchers with optical quality calcium–strontium fluoride crystals with widely varying composition grown under practically identical conditions. As a consequence one can explore possible reasons that can affect the growth mechanism for this or any other systems with a fluoride structure and so provide scope aimed at the future improvement of the crystal quality thereby enlarging the field of mixed fluoride systems’ applications.