Polyhedron, volume 100, pages 132-138
Heterospin complex showing spin transition at room temperature
Romanenko G.
1
,
Barskaya I Yu
1
,
Fedin Matvey
1
,
Maryunina K Yu
3
,
Tretyakov Evgeny
1
,
Sagdeev R. Z.
4
,
2
3
Department of Chemistry, Graduate School of Science, Hiroshima University, 739-8526 Higashi- Hiroshima, Japan
|
Publication type: Journal Article
Publication date: 2015-11-01
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
New nitronyl nitroxides LMe and LMe-CP containing a 4-methylpyridin-3-yl substituent were synthesized. It was found that the interaction of Сu(hfac)2 with LMe and LMe-CP gave binuclear [Cu(hfac)2LMe]2 and [Cu(hfac)2LMe-CP]2·Solv (Solv = n-C6H14, n-C10H22, n-C16H34) and chain polymer {[[Cu(hfac)2]2LMe2][Cu(hfac)2]}∞ heterospin complexes. An important structural peculiarity of LMe and LMe-CP is a large dihedral angle between the planes of the O –N−C N → O paramagnetic fragment and the pyridine ring: 55.2 and 56.1°, respectively. The presence of a methyl group in the pyridine ring of the nitroxide molecule in {[[Cu(hfac)2]2LMe2][Cu(hfac)2]}∞ proved favorable for spin transition at nearly room temperature.
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Tolstikov S. E. et al. Heterospin complex showing spin transition at room temperature // Polyhedron. 2015. Vol. 100. pp. 132-138.
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Tolstikov S. E., Artiukhova N., Romanenko G., Bogomyakov A. S., Zueva E. M., Barskaya I. Yu., Fedin M., Maryunina K. Yu., Tretyakov E., Sagdeev R. Z., Ovcharenko V. Heterospin complex showing spin transition at room temperature // Polyhedron. 2015. Vol. 100. pp. 132-138.
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TY - JOUR
DO - 10.1016/j.poly.2015.07.029
UR - https://doi.org/10.1016%2Fj.poly.2015.07.029
TI - Heterospin complex showing spin transition at room temperature
T2 - Polyhedron
AU - Tolstikov, Svyatoslav E
AU - Artiukhova, Natalia
AU - Romanenko, G.
AU - Bogomyakov, Artem S
AU - Zueva, Ekaterina M
AU - Barskaya, I Yu
AU - Fedin, Matvey
AU - Maryunina, K Yu
AU - Tretyakov, Evgeny
AU - Sagdeev, R. Z.
AU - Ovcharenko, V.
PY - 2015
DA - 2015/11/01 00:00:00
PB - Elsevier
SP - 132-138
VL - 100
SN - 0277-5387
ER -
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@article{2015_Tolstikov,
author = {Svyatoslav E Tolstikov and Natalia Artiukhova and G. Romanenko and Artem S Bogomyakov and Ekaterina M Zueva and I Yu Barskaya and Matvey Fedin and K Yu Maryunina and Evgeny Tretyakov and R. Z. Sagdeev and V. Ovcharenko},
title = {Heterospin complex showing spin transition at room temperature},
journal = {Polyhedron},
year = {2015},
volume = {100},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016%2Fj.poly.2015.07.029},
pages = {132--138},
doi = {10.1016/j.poly.2015.07.029}
}