Polymer, volume 56, pages 256-262

Specific features of the environmental crazing of poly(ethylene terephthalate) fibers

Arzhakova O V ¹

Dolgova A A ¹

Yarysheva L M ¹

Volynskii A L ¹

Bakeev N F ¹

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Faculty of Chemistry, Lomonosov Moscow State University , Leninskie gory, Moscow 119991, Russia. |

Publication type: Journal Article

Publication date: 2015-01-01

Elsevier

Journal: Polymer

Quartile SCImago

Quartile WOS

Impact factor: 4.6

ISSN: 00323861

DOI: 10.1016/j.polymer.2014.11.044

Copy DOI

Materials Chemistry

Organic Chemistry

Polymers and Plastics

Abstract

Tensile drawing of glassy PET fibers via environmental crazing is studied. Direct microscopic observations show that this process includes the development of macroscopic porosity due to the initiation and growth of multiple crazes with their specific fibrillar-porous structure. Environmental crazing of fibers is characterized by the early collapse of the thermodynamically unstable structure of crazes. This process commences at the stage of craze widening and proceeds until the crazes lose their porosity and become fully monolithic. The collapse is provided by the coagulation of the flexible nanoscale craze fibrils via their interaction by side surfaces. The collapse is markedly intensified when the active liquid is removed from the volume of crazes and, as a result, the crazed fibers acquire a specific surface relief with alternating thick and thin regions corresponding to the bulk unoriented polymer and the collapsed crazes. Practical advantages of the stage of the collapse of the crazed nanoporous structure of crazes for the creation of the fiber-based nanocomposite materials are discussed. • Environmental crazing of PET fibers is studied over a wide range of tensile strains. • The mechanism of environmental crazing in fibers is proposed. • Upon EC, the fibers experience an early collapse of the nanoporous craze structure. • Collapse gradually progresses towards complete monolithization of nanoporous crazes. • The benefits of EC for the preparation of nanocomposite materials are highlighted.

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Citations by journals

	1 2 3
Polymer	Polymer, 3, 13.04% Polymer 3 publications, 13.04%
Macromolecular Materials and Engineering	Macromolecular Materials and Engineering, 2, 8.7% Macromolecular Materials and Engineering 2 publications, 8.7%
ACS applied materials & interfaces	ACS applied materials & interfaces, 2, 8.7% ACS applied materials & interfaces 2 publications, 8.7%
Physica B: Condensed Matter	Physica B: Condensed Matter, 2, 8.7% Physica B: Condensed Matter 2 publications, 8.7%
Sensors and Actuators, B: Chemical	Sensors and Actuators, B: Chemical, 1, 4.35% Sensors and Actuators, B: Chemical 1 publication, 4.35%
Polymer Science - Series A	Polymer Science - Series A, 1, 4.35% Polymer Science - Series A 1 publication, 4.35%
European Polymer Journal	European Polymer Journal, 1, 4.35% European Polymer Journal 1 publication, 4.35%
iScience	iScience, 1, 4.35% iScience 1 publication, 4.35%
Materials Today Communications	Materials Today Communications, 1, 4.35% Materials Today Communications 1 publication, 4.35%
Journal of the Mechanics and Physics of Solids	Journal of the Mechanics and Physics of Solids, 1, 4.35% Journal of the Mechanics and Physics of Solids 1 publication, 4.35%
Mendeleev Communications	Mendeleev Communications, 1, 4.35% Mendeleev Communications 1 publication, 4.35%
Solar Energy Materials and Solar Cells	Solar Energy Materials and Solar Cells, 1, 4.35% Solar Energy Materials and Solar Cells 1 publication, 4.35%
Russian Journal of General Chemistry	Russian Journal of General Chemistry, 1, 4.35% Russian Journal of General Chemistry 1 publication, 4.35%
AIP Conference Proceedings	AIP Conference Proceedings, 1, 4.35% AIP Conference Proceedings 1 publication, 4.35%
Polymer Composites	Polymer Composites, 1, 4.35% Polymer Composites 1 publication, 4.35%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 4.35% Russian Chemical Reviews 1 publication, 4.35%
Ceramics International	Ceramics International, 1, 4.35% Ceramics International 1 publication, 4.35%
Colloid Journal	Colloid Journal, 1, 4.35% Colloid Journal 1 publication, 4.35%
	1 2 3

Citations by publishers

	2 4 6 8 10 12 14
Elsevier	Elsevier, 13, 56.52% Elsevier 13 publications, 56.52%
Wiley	Wiley, 3, 13.04% Wiley 3 publications, 13.04%
Pleiades Publishing	Pleiades Publishing, 3, 13.04% Pleiades Publishing 3 publications, 13.04%
American Chemical Society (ACS)	American Chemical Society (ACS), 2, 8.7% American Chemical Society (ACS) 2 publications, 8.7%
American Institute of Physics (AIP)	American Institute of Physics (AIP), 1, 4.35% American Institute of Physics (AIP) 1 publication, 4.35%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 4.35% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 4.35%
	2 4 6 8 10 12 14

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Arzhakova O. V. et al. Specific features of the environmental crazing of poly(ethylene terephthalate) fibers // Polymer. 2015. Vol. 56. pp. 256-262.

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Arzhakova O. V., Dolgova A. A., Yarysheva L. M., Volynskii A. L., Bakeev N. F. Specific features of the environmental crazing of poly(ethylene terephthalate) fibers // Polymer. 2015. Vol. 56. pp. 256-262.

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RIS Copy

TY - JOUR

DO - 10.1016/j.polymer.2014.11.044

UR - https://doi.org/10.1016%2Fj.polymer.2014.11.044

TI - Specific features of the environmental crazing of poly(ethylene terephthalate) fibers

T2 - Polymer

AU - Yarysheva, L M

AU - Volynskii, A L

AU - Bakeev, N F

AU - Arzhakova, O V

AU - Dolgova, A A

PY - 2015

DA - 2015/01/01 00:00:00

PB - Elsevier

SP - 256-262

VL - 56

SN - 0032-3861

ER -

BibTex

Cite this

BibTex Copy

@article{2015_Arzhakova,

author = {L M Yarysheva and A L Volynskii and N F Bakeev and O V Arzhakova and A A Dolgova},

title = {Specific features of the environmental crazing of poly(ethylene terephthalate) fibers},

journal = {Polymer},

year = {2015},

volume = {56},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016%2Fj.polymer.2014.11.044},

pages = {256--262},

doi = {10.1016/j.polymer.2014.11.044}

}

Found error?

Publisher

Elsevier

Journal

Polymer

Quartile SCImago

Quartile WOS

Impact factor

4.6

ISSN

00323861 (Print)

Labs

NILE structures of polymers

Profiles

Arzhakova, Olga V