Polymer, volume 186, pages 122020

“Green” environmental crazing of polymers in oil-in-water emulsions with high water content

Publication typeJournal Article
Publication date2020-01-01
Journal: Polymer
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor4.6
ISSN00323861
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
Abstract This work addresses “green” environmental crazing of polymers in biphase oil-in-water (O/W) emulsions with high water content (above 95 vol %), which can serve as an ecologically safe alternative to pure organic solvents (hydrocarbons and aliphatic alcohols as oils) with respect to their effect on the mechanical behavior of polymers and stress-induced development of porosity via environmental crazing. This approach is shown to be universal for both modes of environmental crazing as intercrystallite crazing for semicrystalline (high-density polyethylene, polytetrafluoroethylene) and classical crazing for amorphous glassy polymers (PET). The mechanism behind the action of the O/W emulsions on polymers is discussed. The applied advantages of the use of the O/W emulsions with high water content for the preparation of mesoporous and nanocomposite polymer materials are highlighted.

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GOST Copy
Arzhakova O. V. et al. “Green” environmental crazing of polymers in oil-in-water emulsions with high water content // Polymer. 2020. Vol. 186. p. 122020.
GOST all authors (up to 50) Copy
Arzhakova O. V., Kopnov A. Yu., Nazarov A. I., Dolgova A. A., Volynskii A. L. “Green” environmental crazing of polymers in oil-in-water emulsions with high water content // Polymer. 2020. Vol. 186. p. 122020.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.polymer.2019.122020
UR - https://doi.org/10.1016%2Fj.polymer.2019.122020
TI - “Green” environmental crazing of polymers in oil-in-water emulsions with high water content
T2 - Polymer
AU - Arzhakova, O V
AU - Kopnov, A Yu
AU - Nazarov, A. I.
AU - Dolgova, A A
AU - Volynskii, A L
PY - 2020
DA - 2020/01/01 00:00:00
PB - Elsevier
SP - 122020
VL - 186
SN - 0032-3861
ER -
BibTex
Cite this
BibTex Copy
@article{2020_Arzhakova,
author = {O V Arzhakova and A Yu Kopnov and A. I. Nazarov and A A Dolgova and A L Volynskii},
title = {“Green” environmental crazing of polymers in oil-in-water emulsions with high water content},
journal = {Polymer},
year = {2020},
volume = {186},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016%2Fj.polymer.2019.122020},
pages = {122020},
doi = {10.1016/j.polymer.2019.122020}
}
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