Surface and Coatings Technology, volume 424, pages 127670

Formation of wear-resistant graphite/diamond-like carbon nanocomposite coatings on Ti using accelerated C60-ions

Publication typeJournal Article
Publication date2021-10-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor5.4
ISSN02578972
Materials Chemistry
Surfaces, Coatings and Films
General Chemistry
Condensed Matter Physics
Surfaces and Interfaces
Abstract
The nanostructural and tribological characteristics of carbon nanocomposite coatings (CNCs), deposited by accelerated C 60 ions at high temperatures, were studied. The CNCs were successfully fabricated on Ti-alloy using a flux that contained C 60 ions with 5 and 10 keV energies. Unlike the previous studies, ion mass-separator was not implemented to the deposition process. This enabled deposition of sp 2 -rich CNCs with a lower coefficient of friction (COF) at a higher deposition rate. Laser confocal microscopy , atomic force microscopy transmission electron microscopy , Raman spectroscopy , X-ray photoelectron spectroscopy, and X-ray Auger Electron Spectroscopy were used to investigate the structure of the coatings and friction test results. A carbon nanocomposite film consisting of graphite nanocrystals enclosed in an amorphous diamond-like matrix was formed at a deposition temperature of 300–400 °C. Upon deposition of the CNC, a COF of ~0.06 was achieved, which was almost one order of magnitude lower than that of bare Ti-alloy substrate. The surface wear was reduced by 360 times. The wear mechanism was changed from abrasive wear (on bare Ti-alloy) to a burnishing smoothening of the surface roughness (on CNCs). The transfer of graphite nanocrystals from the coating to the counter surface was identified and observed to act as a solid lubricant . • Carbon nanocomposite coatings were deposited on Ti using accelerated C 60 -ions. • Graphite nanocrystals embedded in amorphous diamond-like carbon matrix were formed. • The coatings were deposited without the implementation of ion mass-separator. • Deposition temperature significantly affected the size of graphite nanocrystals. • The coatings reduced the COF and wear rate of Ti by 8 and 360 folds, respectively.

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Khadem M. et al. Formation of wear-resistant graphite/diamond-like carbon nanocomposite coatings on Ti using accelerated C60-ions // Surface and Coatings Technology. 2021. Vol. 424. p. 127670.
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Khadem M., Pukha V. E., Penkov O. V., Khodos I. I., Belmesov A. A., Nechaev G. V., Kabachkov E. N., Karaseov P. A., Kim D. Formation of wear-resistant graphite/diamond-like carbon nanocomposite coatings on Ti using accelerated C60-ions // Surface and Coatings Technology. 2021. Vol. 424. p. 127670.
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RIS Copy
TY - JOUR
DO - 10.1016/j.surfcoat.2021.127670
UR - https://doi.org/10.1016%2Fj.surfcoat.2021.127670
TI - Formation of wear-resistant graphite/diamond-like carbon nanocomposite coatings on Ti using accelerated C60-ions
T2 - Surface and Coatings Technology
AU - Khadem, Mahdi
AU - Pukha, Vladimir E
AU - Penkov, Oleksiy V.
AU - Khodos, Igor I.
AU - Belmesov, Andrei A
AU - Nechaev, Grigory V
AU - Kabachkov, Eugene N
AU - Karaseov, Platon A
AU - Kim, DaeEun
PY - 2021
DA - 2021/10/01 00:00:00
PB - Elsevier
SP - 127670
VL - 424
SN - 0257-8972
ER -
BibTex
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BibTex Copy
@article{2021_Khadem,
author = {Mahdi Khadem and Vladimir E Pukha and Oleksiy V. Penkov and Igor I. Khodos and Andrei A Belmesov and Grigory V Nechaev and Eugene N Kabachkov and Platon A Karaseov and DaeEun Kim},
title = {Formation of wear-resistant graphite/diamond-like carbon nanocomposite coatings on Ti using accelerated C60-ions},
journal = {Surface and Coatings Technology},
year = {2021},
volume = {424},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016%2Fj.surfcoat.2021.127670},
pages = {127670},
doi = {10.1016/j.surfcoat.2021.127670}
}
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