Thermochimica Acta, volume 710, pages 179177

Novel adamantane-based dicyanate ester: Synthesis, polymerization kinetics, and thermal properties of resulting polymer

Galukhin Andrey ¹

Nosov Roman ¹

Nikolaev Ilya ¹

Kachmarzhik Alexander ¹

Aleshin Roman ¹

R. Islamov Daut ²

Vyazovkin Sergey ³

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Alexander Butlerov Institute of Chemistry, Kazan Federal University, 18 Kremlevskaya Street, 420008 Kazan, Russian Federation |

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, 8 Arbuzov Street, Kazan, 420088, Russian Federation

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

Department of Chemistry, University of Alabama at Birmingham, 901 S. 14th Street, Birmingham, AL 35294, USA |

Publication type: Journal Article

Publication date: 2022-04-01

Elsevier

Journal: Thermochimica Acta

Quartile SCImago

Quartile WOS

Impact factor: 3.5

ISSN: 00406031, 1872762X

DOI: 10.1016/j.tca.2022.179177

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Physical and Theoretical Chemistry

Condensed Matter Physics

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Abstract

• New adamantane-based dicyanate ester is synthesized. • DSC polymerization kinetics is studied by isoconversional and model based methods. • Polymer is characterized by TGA, TMDSC, and TMA. • Improvement in thermal properties and kinetic changes are linked to structure. A new adamantane-based dicyanate ester has been synthesized. The kinetics of its thermal polymerization is studied by means of conventional and temperature-modulated differential scanning calorimetry. The kinetics is analyzed comprehensively by a combination of an advanced isoconversional and model-fitting method. Polymerization proceeds via transition from a kinetic- to diffusion-control regime, which becomes operative at the later stages of the process. The kinetically-controlled regime manifests itself as a quasi-one-step auto-catalytic reaction. A contribution of diffusion to the overall kinetic is accounted for by means of the Fournier model. The polymerization product possesses excellent thermal properties (the glass transition temperature of ∼370 °C and 5% mass loss temperature of ∼480 °C), which makes it a promising candidate for application in hot-section components for aerospace and military industry.

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Citations by journals

	1 2
Thermochimica Acta	Thermochimica Acta, 2, 28.57% Thermochimica Acta 2 publications, 28.57%
Journal of Chemical & Engineering Data	Journal of Chemical & Engineering Data, 1, 14.29% Journal of Chemical & Engineering Data 1 publication, 14.29%
Macromolecular Chemistry and Physics	Macromolecular Chemistry and Physics, 1, 14.29% Macromolecular Chemistry and Physics 1 publication, 14.29%
Molecules	Molecules, 1, 14.29% Molecules 1 publication, 14.29%
Russian Journal of Organic Chemistry	Russian Journal of Organic Chemistry, 1, 14.29% Russian Journal of Organic Chemistry 1 publication, 14.29%
Organic Process Research and Development	Organic Process Research and Development, 1, 14.29% Organic Process Research and Development 1 publication, 14.29%
	1 2

Citations by publishers

	1 2
American Chemical Society (ACS)	American Chemical Society (ACS), 2, 28.57% American Chemical Society (ACS) 2 publications, 28.57%
Elsevier	Elsevier, 2, 28.57% Elsevier 2 publications, 28.57%
Wiley	Wiley, 1, 14.29% Wiley 1 publication, 14.29%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 14.29% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 14.29%
Pleiades Publishing	Pleiades Publishing, 1, 14.29% Pleiades Publishing 1 publication, 14.29%
	1 2

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Galukhin A. et al. Novel adamantane-based dicyanate ester: Synthesis, polymerization kinetics, and thermal properties of resulting polymer // Thermochimica Acta. 2022. Vol. 710. p. 179177.

GOST all authors (up to 50) Copy

Galukhin A., Nosov R., Nikolaev I., Kachmarzhik A., Aleshin R., R. Islamov D., Vyazovkin S. Novel adamantane-based dicyanate ester: Synthesis, polymerization kinetics, and thermal properties of resulting polymer // Thermochimica Acta. 2022. Vol. 710. p. 179177.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.tca.2022.179177

UR - https://doi.org/10.1016%2Fj.tca.2022.179177

TI - Novel adamantane-based dicyanate ester: Synthesis, polymerization kinetics, and thermal properties of resulting polymer

T2 - Thermochimica Acta

AU - Galukhin, Andrey

AU - Nosov, Roman

AU - Nikolaev, Ilya

AU - Kachmarzhik, Alexander

AU - Aleshin, Roman

AU - R. Islamov, Daut

AU - Vyazovkin, Sergey

PY - 2022

DA - 2022/04/01 00:00:00

PB - Elsevier

SP - 179177

VL - 710

SN - 0040-6031

SN - 1872-762X

ER -

BibTex

Cite this

BibTex Copy

@article{2022_Galukhin,

author = {Andrey Galukhin and Roman Nosov and Ilya Nikolaev and Alexander Kachmarzhik and Roman Aleshin and Daut R. Islamov and Sergey Vyazovkin},

title = {Novel adamantane-based dicyanate ester: Synthesis, polymerization kinetics, and thermal properties of resulting polymer},

journal = {Thermochimica Acta},

year = {2022},

volume = {710},

publisher = {Elsevier},

month = {apr},

url = {https://doi.org/10.1016%2Fj.tca.2022.179177},

pages = {179177},

doi = {10.1016/j.tca.2022.179177}

}

Found error?

Publisher

Elsevier

Journal

Thermochimica Acta

Quartile SCImago

Quartile WOS

Impact factor

3.5

ISSN

00406031 (Print)
1872762X (Electronic)

Labs

Polymer Chemistry

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