Thermochimica Acta, volume 714, pages 179243

ICTAC Kinetics Committee recommendations for analysis of thermal polymerization kinetics

Vyazovkin Sergey ¹

Achilias Dimitris S. ²

Fernández-Francos Xavier ³

Galukhin Andrey ⁴

Sbirrazzuoli Nicolas ⁵

Hide authors affiliations Show authors affiliations: 5 affiliations

Department of Chemistry, University of Alabama at Birmingham, 901 S. 14th Street, Birmingham, AL 35294, USA |

Department of Chemistry, Aristotle University of Thessaloniki, Thessaloniki 54124, Greece |

Thermodynamics Laboratory, ETSEIB, Universitat Politècnica de Catalunya, Av. Diagonal 647, Barcelona 08028, Spain |

⁴

Alexander Butlerov Institute of Chemistry, Kazan Federal University, 18 Kremlevskaya Street, Kazan 420008, Russian Federation |

⁵

UMR CNRS 7272, Institute of Chemistry of Nice, University Côte d'Azur, Nice 06100, France |

Publication type: Journal Article

Publication date: 2022-08-01

Elsevier

Journal: Thermochimica Acta

Quartile SCImago

Quartile WOS

Impact factor: 3.5

ISSN: 00406031, 1872762X

DOI: 10.1016/j.tca.2022.179243

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Physical and Theoretical Chemistry

Condensed Matter Physics

Instrumentation

Abstract

• Recommendations are provided for kinetic analysis of thermal polymerization. • Main focus is on analysis of DSC measurements. • Multi-step nature of polymerization kinetics is emphasized. • Model-fitting, isoconversional, and deconvolution analyses are discussed. • Specific advices are offered for efficient usage of each analysis. The present recommendations have been developed by the Kinetics Committee of the International Confederation for Thermal Analysis and Calorimetry (ICTAC). The recommendations provide guidance on kinetic analysis of thermal polymerization, which incorporates both linear and crosslinking polymerization (curing). The focus is on treating the kinetics as measured by differential scanning calorimetry (DSC). The recommendations discuss basic reaction mechanisms and emphasize the multi-step nature of the polymerization kinetics. An overview of mechanistic and phenomenological models is provided for polymerization controlled by reaction kinetics and diffusion. Three different approaches to evaluation of kinetic parameters (activation energy, preexponential factor, reaction model) for individual steps are considered. These approaches comprise model-fitting, isoconversional, and deconvolution analyses. Practical advices are offered for effective usage of each approach. Attention is paid to the typical problems and to the ways of addressing them. The recommendations are intended to assist with efficiently conducting kinetic analysis and interpreting its results.

By date By citations

Citations by journals

	2 4 6 8 10 12
Thermochimica Acta	Thermochimica Acta, 11, 24.44% Thermochimica Acta 11 publications, 24.44%
Processes	Processes, 4, 8.89% Processes 4 publications, 8.89%
Polymers	Polymers, 4, 8.89% Polymers 4 publications, 8.89%
Macromolecules	Macromolecules, 2, 4.44% Macromolecules 2 publications, 4.44%
Macromolecular Chemistry and Physics	Macromolecular Chemistry and Physics, 1, 2.22% Macromolecular Chemistry and Physics 1 publication, 2.22%
Thermo	Thermo, 1, 2.22% Thermo 1 publication, 2.22%
Renewable Energy	Renewable Energy, 1, 2.22% Renewable Energy 1 publication, 2.22%
Energies	Energies, 1, 2.22% Energies 1 publication, 2.22%
Polymer Degradation and Stability	Polymer Degradation and Stability, 1, 2.22% Polymer Degradation and Stability 1 publication, 2.22%
Progress in Organic Coatings	Progress in Organic Coatings, 1, 2.22% Progress in Organic Coatings 1 publication, 2.22%
Reaction Kinetics, Mechanisms and Catalysis	Reaction Kinetics, Mechanisms and Catalysis, 1, 2.22% Reaction Kinetics, Mechanisms and Catalysis 1 publication, 2.22%
Journal of Polymer Research	Journal of Polymer Research, 1, 2.22% Journal of Polymer Research 1 publication, 2.22%
Journal of Reinforced Plastics and Composites	Journal of Reinforced Plastics and Composites, 1, 2.22% Journal of Reinforced Plastics and Composites 1 publication, 2.22%
International Journal of Green Energy	International Journal of Green Energy, 1, 2.22% International Journal of Green Energy 1 publication, 2.22%
Polymer	Polymer, 1, 2.22% Polymer 1 publication, 2.22%
Polymers from Renewable Resources	Polymers from Renewable Resources, 1, 2.22% Polymers from Renewable Resources 1 publication, 2.22%
Reactive and Functional Polymers	Reactive and Functional Polymers, 1, 2.22% Reactive and Functional Polymers 1 publication, 2.22%
Macromolecular Materials and Engineering	Macromolecular Materials and Engineering, 1, 2.22% Macromolecular Materials and Engineering 1 publication, 2.22%
Journal of Industrial and Engineering Chemistry	Journal of Industrial and Engineering Chemistry, 1, 2.22% Journal of Industrial and Engineering Chemistry 1 publication, 2.22%
Materials	Materials, 1, 2.22% Materials 1 publication, 2.22%
Energy Science and Engineering	Energy Science and Engineering, 1, 2.22% Energy Science and Engineering 1 publication, 2.22%
Polymer Testing	Polymer Testing, 1, 2.22% Polymer Testing 1 publication, 2.22%
Macromolecular Theory and Simulations	Macromolecular Theory and Simulations, 1, 2.22% Macromolecular Theory and Simulations 1 publication, 2.22%
Chemical Engineering Journal	Chemical Engineering Journal, 1, 2.22% Chemical Engineering Journal 1 publication, 2.22%
Journal of Thermal Analysis and Calorimetry	Journal of Thermal Analysis and Calorimetry, 1, 2.22% Journal of Thermal Analysis and Calorimetry 1 publication, 2.22%
Biofuels, Bioproducts and Biorefining	Biofuels, Bioproducts and Biorefining, 1, 2.22% Biofuels, Bioproducts and Biorefining 1 publication, 2.22%
Theoretical Foundations of Chemical Engineering	Theoretical Foundations of Chemical Engineering, 1, 2.22% Theoretical Foundations of Chemical Engineering 1 publication, 2.22%
ACS Applied Polymer Materials	ACS Applied Polymer Materials, 1, 2.22% ACS Applied Polymer Materials 1 publication, 2.22%
	2 4 6 8 10 12

Citations by publishers

	2 4 6 8 10 12 14 16 18
Elsevier	Elsevier, 18, 40% Elsevier 18 publications, 40%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 11, 24.44% Multidisciplinary Digital Publishing Institute (MDPI) 11 publications, 24.44%
Wiley	Wiley, 5, 11.11% Wiley 5 publications, 11.11%
American Chemical Society (ACS)	American Chemical Society (ACS), 3, 6.67% American Chemical Society (ACS) 3 publications, 6.67%
Springer Nature	Springer Nature, 3, 6.67% Springer Nature 3 publications, 6.67%
SAGE	SAGE, 2, 4.44% SAGE 2 publications, 4.44%
Taylor & Francis	Taylor & Francis, 1, 2.22% Taylor & Francis 1 publication, 2.22%
Korean Society of Industrial Engineering Chemistry	Korean Society of Industrial Engineering Chemistry, 1, 2.22% Korean Society of Industrial Engineering Chemistry 1 publication, 2.22%
Pleiades Publishing	Pleiades Publishing, 1, 2.22% Pleiades Publishing 1 publication, 2.22%
	2 4 6 8 10 12 14 16 18

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Vyazovkin S. et al. ICTAC Kinetics Committee recommendations for analysis of thermal polymerization kinetics // Thermochimica Acta. 2022. Vol. 714. p. 179243.

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Vyazovkin S., Achilias D. S., Fernández-Francos X., Galukhin A., Sbirrazzuoli N. ICTAC Kinetics Committee recommendations for analysis of thermal polymerization kinetics // Thermochimica Acta. 2022. Vol. 714. p. 179243.

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TY - JOUR

DO - 10.1016/j.tca.2022.179243

UR - https://doi.org/10.1016%2Fj.tca.2022.179243

TI - ICTAC Kinetics Committee recommendations for analysis of thermal polymerization kinetics

T2 - Thermochimica Acta

AU - Vyazovkin, Sergey

AU - Achilias, Dimitris S.

AU - Fernández-Francos, Xavier

AU - Galukhin, Andrey

AU - Sbirrazzuoli, Nicolas

PY - 2022

DA - 2022/08/01 00:00:00

PB - Elsevier

SP - 179243

VL - 714

SN - 0040-6031

SN - 1872-762X

ER -

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BibTex Copy

@article{2022_Vyazovkin,

author = {Sergey Vyazovkin and Dimitris S. Achilias and Xavier Fernández-Francos and Andrey Galukhin and Nicolas Sbirrazzuoli},

title = {ICTAC Kinetics Committee recommendations for analysis of thermal polymerization kinetics},

journal = {Thermochimica Acta},

year = {2022},

volume = {714},

publisher = {Elsevier},

month = {aug},

url = {https://doi.org/10.1016%2Fj.tca.2022.179243},

pages = {179243},

doi = {10.1016/j.tca.2022.179243}

}

Found error?

Publisher

Elsevier

Journal

Thermochimica Acta

Quartile SCImago

Quartile WOS

Impact factor

3.5

ISSN

00406031 (Print)
1872762X (Electronic)

Labs

Polymer Chemistry

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