Iridium-catalyzed asymmetric hydrogenation of 2-substituted 1,4-benzodioxines
Publication type: Journal Article
Publication date: 2018-01-01
scimago Q3
wos Q2
SJR: 0.426
CiteScore: 4.1
Impact factor: 2.2
ISSN: 00404020, 14645416
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
An Ir-catalyzed asymmetric hydrogenation of 2-substituted 1,4-benzodioxines was developed for the preparation of chiral 1,4-benzodioxanes, which are present in numerous biologically active compounds and natural products. Our tropos biphenyl phosphine-oxazoline ligand is essential for obtaining good ee. A broad range of substrates were tolerable to the reaction conditions and gave the corresponding hydrogenation products in excellent yields and with moderate to good enantioselectivities using the Ir-complex of our tropos phosphine-oxazoline ligand.
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GOST
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Wang Y. et al. Iridium-catalyzed asymmetric hydrogenation of 2-substituted 1,4-benzodioxines // Tetrahedron. 2018. Vol. 74. No. 4. pp. 477-482.
GOST all authors (up to 50)
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Wang Y., Xia J., Yang G., Zhang W. Iridium-catalyzed asymmetric hydrogenation of 2-substituted 1,4-benzodioxines // Tetrahedron. 2018. Vol. 74. No. 4. pp. 477-482.
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RIS
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TY - JOUR
DO - 10.1016/j.tet.2017.12.015
UR - https://doi.org/10.1016/j.tet.2017.12.015
TI - Iridium-catalyzed asymmetric hydrogenation of 2-substituted 1,4-benzodioxines
T2 - Tetrahedron
AU - Wang, Yanzhao
AU - Xia, Jingzhao
AU - Yang, Guoqiang
AU - Zhang, Wanbin
PY - 2018
DA - 2018/01/01
PB - Elsevier
SP - 477-482
IS - 4
VL - 74
SN - 0040-4020
SN - 1464-5416
ER -
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BibTex (up to 50 authors)
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@article{2018_Wang,
author = {Yanzhao Wang and Jingzhao Xia and Guoqiang Yang and Wanbin Zhang},
title = {Iridium-catalyzed asymmetric hydrogenation of 2-substituted 1,4-benzodioxines},
journal = {Tetrahedron},
year = {2018},
volume = {74},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.tet.2017.12.015},
number = {4},
pages = {477--482},
doi = {10.1016/j.tet.2017.12.015}
}
Cite this
MLA
Copy
Wang, Yanzhao, et al. “Iridium-catalyzed asymmetric hydrogenation of 2-substituted 1,4-benzodioxines.” Tetrahedron, vol. 74, no. 4, Jan. 2018, pp. 477-482. https://doi.org/10.1016/j.tet.2017.12.015.