Elsevier
Tetrahedron
,  volume 173 ,  pages 134472

One-pot multistep carboxylation–oxidation of cage compounds

Publication type: Journal Article
Publication date: 2025-03-01
Elsevier
scimago Q3
wos Q2
SJR: 0.426
CiteScore: 4.1
Impact factor: 2.2
ISSN: 00404020, 14645416
Abstract
An efficient one-pot approach to the synthesis of substituted 3-hydroxyadamantane-1-carboxylic acids has been developed. The method is based on the sequential combination of carboxylation by the Koch-Haaf reaction and oxidation in the presence of HNO3 in H2SO4 or H2SO4·SO3 medium, which allows COOH and OH to be appended together into the adamantane skeleton in the same reaction vessel. Due to their diverse functionality, the obtained compounds can be used as building blocks for the synthesis of new adamantane compounds with a many field of applications.
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GOST Copy
Ivleva E. I. et al. One-pot multistep carboxylation–oxidation of cage compounds // Tetrahedron. 2025. Vol. 173. p. 134472.
GOST all authors (up to 50) Copy
Ivleva E. I., Khatmullina Y. E., Skomorokhov M. Y., Klimochkin Y. N. One-pot multistep carboxylation–oxidation of cage compounds // Tetrahedron. 2025. Vol. 173. p. 134472.
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RIS Copy
TY - JOUR
DO - 10.1016/j.tet.2025.134472
UR - https://linkinghub.elsevier.com/retrieve/pii/S0040402025000286
TI - One-pot multistep carboxylation–oxidation of cage compounds
T2 - Tetrahedron
AU - Ivleva, Elena I.
AU - Khatmullina, Yulia E.
AU - Skomorokhov, Mikhail Yu.
AU - Klimochkin, Yuri N.
PY - 2025
DA - 2025/03/01
PB - Elsevier
SP - 134472
VL - 173
SN - 0040-4020
SN - 1464-5416
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2025_Ivleva,
author = {Elena I. Ivleva and Yulia E. Khatmullina and Mikhail Yu. Skomorokhov and Yuri N. Klimochkin},
title = {One-pot multistep carboxylation–oxidation of cage compounds},
journal = {Tetrahedron},
year = {2025},
volume = {173},
publisher = {Elsevier},
month = {mar},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0040402025000286},
pages = {134472},
doi = {10.1016/j.tet.2025.134472}
}
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