Chiral 1,4-bis-diphosphine ligands from optically active (Z)-olefines
Publication type: Journal Article
Publication date: 2007-06-21
Catalysis
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The catalytic asymmetric hydrogenation of prochiral ketones was carried out with Ru(II) complexes prepared from new chiral diphosphine ligands, cis -( R , R )-2,5-bis[(diarylphosphino)]-3-hexenes. These new ligands were prepared from enantiomerically pure ( R , R ) or ( S , S )-( Z )-3-hexene-2,5 diol and enantiomeric excesses up to 85% were obtained in the reduction of 2-benzamidomethyl-3-oxobutanoate, starting material for the synthesis of 4-acetoxy-2-azetidinone.
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13
Total citations:
13
Citations from 2024:
2
(15.38%)
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Cesarotti E. et al. Chiral 1,4-bis-diphosphine ligands from optically active (Z)-olefines // Tetrahedron Asymmetry. 2007. Vol. 18. No. 11. pp. 1278-1283.
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Cesarotti E., Rimoldi I., Spalluto P., Demartin F. Chiral 1,4-bis-diphosphine ligands from optically active (Z)-olefines // Tetrahedron Asymmetry. 2007. Vol. 18. No. 11. pp. 1278-1283.
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RIS
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TY - JOUR
DO - 10.1016/j.tetasy.2007.04.018
UR - https://doi.org/10.1016/j.tetasy.2007.04.018
TI - Chiral 1,4-bis-diphosphine ligands from optically active (Z)-olefines
T2 - Tetrahedron Asymmetry
AU - Cesarotti, Edoardo
AU - Rimoldi, Isabella
AU - Spalluto, Paola
AU - Demartin, F.
PY - 2007
DA - 2007/06/21
PB - Elsevier
SP - 1278-1283
IS - 11
VL - 18
SN - 0957-4166
SN - 1362-511X
ER -
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BibTex (up to 50 authors)
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@article{2007_Cesarotti,
author = {Edoardo Cesarotti and Isabella Rimoldi and Paola Spalluto and F. Demartin},
title = {Chiral 1,4-bis-diphosphine ligands from optically active (Z)-olefines},
journal = {Tetrahedron Asymmetry},
year = {2007},
volume = {18},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.tetasy.2007.04.018},
number = {11},
pages = {1278--1283},
doi = {10.1016/j.tetasy.2007.04.018}
}
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MLA
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Cesarotti, Edoardo, et al. “Chiral 1,4-bis-diphosphine ligands from optically active (Z)-olefines.” Tetrahedron Asymmetry, vol. 18, no. 11, Jun. 2007, pp. 1278-1283. https://doi.org/10.1016/j.tetasy.2007.04.018.