Palladium-catalyzed carbonylative coupling of benzyl chlorides with aryl boronic acids in aqueous media
Publication type: Journal Article
Publication date: 2010-11-01
scimago Q3
wos Q3
SJR: 0.334
CiteScore: 3.2
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
A novel chemoselective protocol for the carbonylative Suzuki coupling of benzyl chlorides with aryl boronic acids at low pressure of carbon monoxide has been developed. Applying a commercially available palladium acetate/PCy3 catalyst system in the presence of potassium phosphate as the base and water as the solvent the coupling reactions proceeded smoothly. To demonstrate the general applicability 12 different α-arylated acetophenones have been synthesized in moderate to good yields (41–78%) under mild conditions.
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67
Total citations:
67
Citations from 2024:
5
(7.47%)
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MLA
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GOST
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Wu X., Neumann H., Beller M. Palladium-catalyzed carbonylative coupling of benzyl chlorides with aryl boronic acids in aqueous media // Tetrahedron Letters. 2010. Vol. 51. No. 47. pp. 6146-6149.
GOST all authors (up to 50)
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Wu X., Neumann H., Beller M. Palladium-catalyzed carbonylative coupling of benzyl chlorides with aryl boronic acids in aqueous media // Tetrahedron Letters. 2010. Vol. 51. No. 47. pp. 6146-6149.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.tetlet.2010.09.078
UR - https://doi.org/10.1016/j.tetlet.2010.09.078
TI - Palladium-catalyzed carbonylative coupling of benzyl chlorides with aryl boronic acids in aqueous media
T2 - Tetrahedron Letters
AU - Wu, Xiao-Feng
AU - Neumann, Helfried
AU - Beller, Matthias
PY - 2010
DA - 2010/11/01
PB - Elsevier
SP - 6146-6149
IS - 47
VL - 51
SN - 0040-4039
SN - 1873-3581
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2010_Wu,
author = {Xiao-Feng Wu and Helfried Neumann and Matthias Beller},
title = {Palladium-catalyzed carbonylative coupling of benzyl chlorides with aryl boronic acids in aqueous media},
journal = {Tetrahedron Letters},
year = {2010},
volume = {51},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/j.tetlet.2010.09.078},
number = {47},
pages = {6146--6149},
doi = {10.1016/j.tetlet.2010.09.078}
}
Cite this
MLA
Copy
Wu, Xiao-Feng, et al. “Palladium-catalyzed carbonylative coupling of benzyl chlorides with aryl boronic acids in aqueous media.” Tetrahedron Letters, vol. 51, no. 47, Nov. 2010, pp. 6146-6149. https://doi.org/10.1016/j.tetlet.2010.09.078.