Water Research

, volume 42 , issue 8-9 , pages 1935-1942

Reaction of chlorine dioxide with emergent water pollutants: Product study of the reaction of three β-lactam antibiotics with ClO2

Sergio Navalón ¹

M ALVARO ¹

Hermenegildo García ¹

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Department of Chemistry, Universidad Politécnica de Valencia, Camino de Vera S/N, 46022 Valencia, Spain |

Publication type: Journal Article

Publication date: 2008-04-01

Elsevier

Water Research

scimago Q1

wos Q1

SJR: 3.843

CiteScore: 21.2

Impact factor: 12.4

ISSN: 00431354, 18792448

DOI: 10.1016/j.watres.2007.11.023

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PubMed ID: 18093633

Environmental Engineering

Pollution

Civil and Structural Engineering

Waste Management and Disposal

Water Science and Technology

Ecological Modeling

Abstract

This work deals with the chlorine dioxide (ClO(2)) reactivity with three representative beta-lactam antibiotics (penicillin, amoxicillin and cefadroxil) that can be present in natural aquatic resources. Due to the wide use of ClO(2) as disinfection agent our work is of interest to determine the fate of these antibiotics during the water treatment process. Our study shows that antibiotics react stoichiometrically with ClO(2) because increasing amounts of ClO(2) lead to increasing antibiotic disappearance. Concerning the influence of antibiotic structure, penicillin reacts sluggishly with ClO(2), whereas amoxicillin and cefadroxil are highly reactive at either neutral or basic pH. For both reactive antibiotics, hydroquinone together with a wide range of 4-substituted phenols were detected as products. Pretreatment with ClO(2) before chlorination of aqueous solutions of antibiotics reduces the trihalomethane formation as compared with analogous chlorination without ClO(2) pretreatment.

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113

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GOST |

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GOST Copy

Navalón S., ALVARO M., García H. Reaction of chlorine dioxide with emergent water pollutants: Product study of the reaction of three β-lactam antibiotics with ClO2 // Water Research. 2008. Vol. 42. No. 8-9. pp. 1935-1942.

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RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.watres.2007.11.023

UR - https://doi.org/10.1016/j.watres.2007.11.023

TI - Reaction of chlorine dioxide with emergent water pollutants: Product study of the reaction of three β-lactam antibiotics with ClO2

T2 - Water Research

AU - Navalón, Sergio

AU - ALVARO, M

AU - García, Hermenegildo

PY - 2008

DA - 2008/04/01

PB - Elsevier

SP - 1935-1942

IS - 8-9

VL - 42

PMID - 18093633

SN - 0043-1354

SN - 1879-2448

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2008_Navalón,

author = {Sergio Navalón and M ALVARO and Hermenegildo García},

title = {Reaction of chlorine dioxide with emergent water pollutants: Product study of the reaction of three β-lactam antibiotics with ClO2},

journal = {Water Research},

year = {2008},

volume = {42},

publisher = {Elsevier},

month = {apr},

url = {https://doi.org/10.1016/j.watres.2007.11.023},

number = {8-9},

pages = {1935--1942},

doi = {10.1016/j.watres.2007.11.023}

}

MLA

Cite this

MLA Copy

Navalón, Sergio, et al. “Reaction of chlorine dioxide with emergent water pollutants: Product study of the reaction of three β-lactam antibiotics with ClO2.” Water Research, vol. 42, no. 8-9, Apr. 2008, pp. 1935-1942. https://doi.org/10.1016/j.watres.2007.11.023.

Publisher

Elsevier

Journal

Water Research

scimago Q1

wos Q1

SJR

3.843

CiteScore

21.2

Impact factor

12.4

ISSN

00431354 (Print)

18792448 (Electronic)