volume 65 issue 1 pages 177-187

The adsorption of corypalline and related compounds on a pyrolytic graphite electrode

Publication typeJournal Article
Publication date1973-06-01
scimago Q1
wos Q1
SJR1.004
CiteScore10.4
Impact factor6.0
ISSN00032670, 18734324
Biochemistry
Spectroscopy
Analytical Chemistry
Environmental Chemistry
Abstract
Anodic current-time curves have been used to study the adsorption, from TEAP-acetonitrile solution, of corypalline (7-hydroxy-6-methoxy-N-methyl-1,2,3,4-tetrahydroisoquinoline), isocorypalline (6-hydroxy-7-methoxy-N-methyl-1,2,3,4-tetrahydroisoquinoline), and 1-methyl-corypalline. A comparison with analogous cathodic current-time curves obtained with methylene blue leads to the conclusion that, on a pyrolytic graphite electrode, these isoquinoline compounds are adsorbed in a “flat-on” configuration. This conclusion is in harmony with the postulation that the known steroselective, stereospecific oxidative coupling of 1-methylcorypal-line occurs through the adsorption of the reacting molecules on the electrode surface.
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Braun R. D., Stock J. T. The adsorption of corypalline and related compounds on a pyrolytic graphite electrode // Analytica Chimica Acta. 1973. Vol. 65. No. 1. pp. 177-187.
GOST all authors (up to 50) Copy
Braun R. D., Stock J. T. The adsorption of corypalline and related compounds on a pyrolytic graphite electrode // Analytica Chimica Acta. 1973. Vol. 65. No. 1. pp. 177-187.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/s0003-2670(01)80176-8
UR - https://doi.org/10.1016/s0003-2670(01)80176-8
TI - The adsorption of corypalline and related compounds on a pyrolytic graphite electrode
T2 - Analytica Chimica Acta
AU - Braun, Robert D.
AU - Stock, John T.
PY - 1973
DA - 1973/06/01
PB - Elsevier
SP - 177-187
IS - 1
VL - 65
SN - 0003-2670
SN - 1873-4324
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{1973_Braun,
author = {Robert D. Braun and John T. Stock},
title = {The adsorption of corypalline and related compounds on a pyrolytic graphite electrode},
journal = {Analytica Chimica Acta},
year = {1973},
volume = {65},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/s0003-2670(01)80176-8},
number = {1},
pages = {177--187},
doi = {10.1016/s0003-2670(01)80176-8}
}
MLA
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MLA Copy
Braun, Robert D., and John T. Stock. “The adsorption of corypalline and related compounds on a pyrolytic graphite electrode.” Analytica Chimica Acta, vol. 65, no. 1, Jun. 1973, pp. 177-187. https://doi.org/10.1016/s0003-2670(01)80176-8.