Elsevier
Carbohydrate Research
,  volume 21 ,  issue 1 ,  pages 1-8

A new synthesis of 1-deoxy-D-manno-heptulose

Publication type: Journal Article
Publication date: 1972-01-01
Elsevier
scimago Q3
wos Q2
SJR: 0.423
CiteScore: 4.0
Impact factor: 2.5
ISSN: 00086215, 1873426X
Organic Chemistry
Biochemistry
General Medicine
Analytical Chemistry
Abstract
Reaction of 4- O -benzoyl-2,3:5,6-di- O -isopropylidene- D -mannononitrile with methylmagnesium iodide produced 1-benzamido-1-deoxy-2,3:5,6-di- O -isopropylidene-1,1- C -dimethyl- D -mannitol (7) (25.4%) and 1-deoxy-3,4:6,7-di- O -isopropylidene- keto - D - manno -heptulosimine (3) (51.3 %). The structure of the first compound was established by hydrolysis to 1-benzamido-1-deoxy-1,1- C -dimethyl- D -mannitol subsequently degraded to 2-benzamido-2-methylpropanal. Hydrolysis of the second compound gave 1-deoxy- D - manno -heptulose.
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GOST |
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GOST Copy
Kampf A., Dimant E. A new synthesis of 1-deoxy-D-manno-heptulose // Carbohydrate Research. 1972. Vol. 21. No. 1. pp. 1-8.
GOST all authors (up to 50) Copy
Kampf A., Dimant E. A new synthesis of 1-deoxy-D-manno-heptulose // Carbohydrate Research. 1972. Vol. 21. No. 1. pp. 1-8.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/s0008-6215(00)81724-3
UR - https://doi.org/10.1016/s0008-6215(00)81724-3
TI - A new synthesis of 1-deoxy-D-manno-heptulose
T2 - Carbohydrate Research
AU - Kampf, A
AU - Dimant, E.
PY - 1972
DA - 1972/01/01
PB - Elsevier
SP - 1-8
IS - 1
VL - 21
SN - 0008-6215
SN - 1873-426X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1972_Kampf,
author = {A Kampf and E. Dimant},
title = {A new synthesis of 1-deoxy-D-manno-heptulose},
journal = {Carbohydrate Research},
year = {1972},
volume = {21},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/s0008-6215(00)81724-3},
number = {1},
pages = {1--8},
doi = {10.1016/s0008-6215(00)81724-3}
}
MLA
Cite this
MLA Copy
Kampf, A., and E. Dimant. “A new synthesis of 1-deoxy-D-manno-heptulose.” Carbohydrate Research, vol. 21, no. 1, Jan. 1972, pp. 1-8. https://doi.org/10.1016/s0008-6215(00)81724-3.